1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-

Base Information

Chemical Name:1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-
CAS No.:540492-51-1
Molecular Formula:C17H26NP
Molecular Weight:275.36900
Hs Code.:
DSSTox Substance ID:DTXSID80478900
Nikkaji Number:J2.163.333J
Mol file:540492-51-1.mol

Synonyms:540492-51-1;1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-;1-di(propan-2-yl)phosphanyl-N,N-dimethyl-1H-inden-2-amine;1-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(contains vinylic isomer);1-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene;SCHEMBL14822448;DTXSID80478900;CS-0099027

Suppliers and Price of 1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
1-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene, 99%
1g
$ 261.00

Strem Chemicals
1-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene, 99%
250mg
$ 87.00

American Custom Chemicals Corporation
1-DI-I-PROPYLPHOSPHINO-2-(N,N-DIMETHYLAMINO)-1H-INDENE 95.00%
1G
$ 525.00

Total 8 raw suppliers

Chemical Property of 1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-

Chemical Property:

PSA：16.83000
LogP:4.94250
Sensitive.:air sensitive
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:275.180286831
Heavy Atom Count:19
Complexity:324

Purity/Quality:

98% ^*data from raw suppliers

1-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene, 99% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)P(C1C2=CC=CC=C2C=C1N(C)C)C(C)C

Technology Process of 1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl-

There total 1 articles about 1H-Inden-2-amine, 1-[bis(1-methylethyl)phosphino]-N,N-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 40244-90-4
Chlorodiisopropylphosphane

: 35336-08-4
2-N,N-dimethylaminoindene

: 540492-51-1
1-diisopropylphosphino-2-dimethylaminoindene

Guidance literature:: 2-N,N-dimethylaminoindene; With n-butyllithium; In tetrahydrofuran; hexane; at -80 - 20 ℃; for 3h;

Chlorodiisopropylphosphane; In tetrahydrofuran; hexane; at -80 - 20 ℃; for 15h;
DOI:10.1021/ja034543v

Reference yield: 94.0%

: 14104-20-2
silver tetrafluoroborate

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 540492-51-1
1-diisopropylphosphino-2-dimethylaminoindene

: 540492-54-4
[Rh(1,5-cyclooctadiene)(C9H6(N(CH3)2)(P(CH(CH3)2)2))][BF4]

Guidance literature:: In tetrahydrofuran; under N2 atm. to soln. Rh complex in THF soln. ligand in THF was added and stirred for 5 min, AgBF4 was added and stirred for 1 h; soln. was filtered through Celite and evapd. in vacuo; elem. anal.;
DOI:10.1021/om060758c