8-Iodo-2,6-dimethyloct-2-ene

Base Information

• Chemical Name: 8-Iodo-2,6-dimethyloct-2-ene
• CAS No.: 55816-07-4
• Molecular Formula: C10H19I
• Molecular Weight: 266.165
• DSSTox Substance ID: DTXSID30526809
• Mol file: 55816-07-4.mol

Synonyms:8-iodo-2,6-dimethyloct-2-ene;55816-07-4;citronellyl iodide;8-iodo-2,6-dimethyl-oct-2-ene;SCHEMBL9632911;DTXSID30526809;KJQRNGOXCJYIGL-UHFFFAOYSA-N;AKOS040768172

Chemical Property of 8-Iodo-2,6-dimethyloct-2-ene

Chemical Property:

• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 266.05315
• Heavy Atom Count: 11
• Complexity: 112

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(CCC=C(C)C)CCI

Technology Process of 8-Iodo-2,6-dimethyloct-2-ene

There total 1 articles about 8-Iodo-2,6-dimethyloct-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8,8-Diiodo-2,6-dimethyl-2-octene (85390-86-9) → citronellyl iodide (55816-07-4) + carane (554-59-6) + 1-Iodo-2-(2-propenyl)-5-methylcyclohexane (85390-89-2) + cis-3,7-Dimethyl-1-iodo-1,6-octadiene (85390-87-0) + trans-3,7-Dimethyl-1-iodo-1,6-octadiene (85390-88-1)

Guidance literature:

In diethyl ether; for 2h; Product distribution; Irradiation; solvent: (CH₂Cl)2;

DOI:10.1021/jo00160a029

Reference yield: 95.0%

butyl phenyl sulfone (16823-62-4) + (R)-3,7-dimethyl-6-octenyl iodide (55816-07-4,59182-95-5,145678-85-9,69308-74-3) → (4RS,7R)-7,11-dimethyldodec-10-en-4-yl(phenyl)sulfone (1361023-03-1)

Guidance literature:

butyl phenyl sulfone; With n-butyllithium; In tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; hexane; at -40 ℃; for 0.5h; Inert atmosphere;

(R)-3,7-dimethyl-6-octenyl iodide; In tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; hexane; at -40 - 20 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c2ob06906g

Reference yield: 87.0%

(R)-3,7-dimethyl-6-octenyl iodide (55816-07-4,59182-95-5,145678-85-9,69308-74-3) + (2S,6R)-8-(benzyloxy)-1-(phenylsulfonyl)-2,6-dimethyloctane (156592-97-1) → (3R,7S,11R)-1-benzyloxy-3,7,11,15-tetramethyl-8-phenylsulfonyl-14-hexadecene (218461-99-5)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran; hexane; at -25 ℃; for 4h;

DOI:10.1246/bcsj.71.2419

upstream raw materials:

8,8-Diiodo-2,6-dimethyl-2-octene

Downstream raw materials:

(E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene

dihydromyrcene

trans-8-p-menthene

1-(1-Isocyano-4,8-dimethyl-non-7-ene-1-sulfonyl)-4-methyl-benzene