Cyclohexene, 1-methoxy-2-methyl-

Base Information

• Chemical Name: Cyclohexene, 1-methoxy-2-methyl-
• CAS No.: 1728-38-7
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• DSSTox Substance ID: DTXSID80469217
• Nikkaji Number: J781.351A
• Wikidata: Q82296834
• Mol file: 1728-38-7.mol

Synonyms:Cyclohexene, 1-methoxy-2-methyl-;1728-38-7;SCHEMBL6846534;DTXSID80469217

Chemical Property of Cyclohexene, 1-methoxy-2-methyl-

Chemical Property:

• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 126.104465066
• Heavy Atom Count: 9
• Complexity: 125

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(CCCC1)OC

Technology Process of Cyclohexene, 1-methoxy-2-methyl-

There total 9 articles about Cyclohexene, 1-methoxy-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methylcyclohexanone (583-60-8) + trimethyl orthoformate (149-73-5) → Methyl formate (107-31-3) + methyl enol ether of 2-methylcyclohexanone (1728-38-7) + 2-methoxy-3-methylcyclohex-1-ene (1728-37-6)

Guidance literature:

toluene-4-sulfonic acid; In methanol; Yields of byproduct given. Title compound not separated from byproducts; 1) 2 h, 2) 140 deg C;

Reference yield:

trimethylsilyl trifluoromethanesulfonate (27607-77-8) + 1,1-dimethoxy-2-methylcyclohexane (38574-09-3) → methyl enol ether of 2-methylcyclohexanone (1728-38-7) + 2-methoxy-3-methylcyclohex-1-ene (1728-37-6)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00258a043

Reference yield:

2-methoxy-3-methylcyclohex-1-ene (1728-37-6) → methyl enol ether of 2-methylcyclohexanone (1728-38-7)

Guidance literature:

With iodine; In cyclohexane; at 25 ℃; Equilibrium constant; Thermodynamic data;

DOI:10.1021/jo00835a036

upstream raw materials:

2-methoxy-3-methylcyclohex-1-ene

2-Methylcyclohexanone

trimethyl orthoformate

trimethylsilyl trifluoromethanesulfonate

Downstream raw materials:

(S)-(-)-2-(trans-but-2-enyl)-2-methylcyclohexanone

(R)-(+)-2-(trans-but-2-enyl)-2-methylcyclohexanone

2-(buta-1,2-dienyl)-2-methylcyclohexanone

1,10-dimethyl-8,7,15,16-tetraoxa-dispiro<5,2,5,2>hexadecane