1-Phenylselanylpropylselanylbenzene

Base Information

• Chemical Name: 1-Phenylselanylpropylselanylbenzene
• CAS No.: 56814-39-2
• Molecular Formula: C15H16Se2
• Molecular Weight: 354.212
• DSSTox Substance ID: DTXSID00558596
• Wikidata: Q82440957
• Mol file: 56814-39-2.mol

Synonyms:56814-39-2;DTXSID00558596;1,1'-(Propane-1,1-diyldiselanyl)dibenzene

Chemical Property of 1-Phenylselanylpropylselanylbenzene

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 355.95824
• Heavy Atom Count: 17
• Complexity: 173

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC([Se]C1=CC=CC=C1)[Se]C2=CC=CC=C2

Technology Process of 1-Phenylselanylpropylselanylbenzene

There total 2 articles about 1-Phenylselanylpropylselanylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

bis(phenylseleno)methane (20343-90-2) + ethyl iodide (75-03-6) → 1,1-bis(phenylseleno)propane (56814-39-2)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; 1.) -78 deg C, 10 min, 2.) room temperature, overnight;

DOI:10.1021/jo961854y

Reference yield:

→ 1,1-bis(phenylseleno)propane (56814-39-2)

Guidance literature:

Selenophenol, Vinylphenylselenid 10;

Reference yield:

1,1-bis(phenylseleno)propane (56814-39-2) + benzaldehyde (100-52-7) → butyl phenyl selenide (28622-61-9) + 1-phenyl-2-phenylselenobutane-1-ol (72474-92-1)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -78 deg C, 0.1 h; 2.) THF, hexane, -78 deg C, 0.25 h;

DOI:10.1016/S0040-4020(01)80063-6

upstream raw materials:

bis(phenylseleno)methane

ethyl iodide

Downstream raw materials:

butyl phenyl selenide

1-phenyl-2-phenylselenobutane-1-ol

3-Phenylselanyl-decan-4-ol