Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)-

Base Information

• Chemical Name: Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)-
• CAS No.: 58567-43-4
• Molecular Formula: C16H17NO2S
• Molecular Weight: 287.382
• DSSTox Substance ID: DTXSID40454008
• Nikkaji Number: J738.086K
• Mol file: 58567-43-4.mol

Synonyms:58567-43-4;Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)-;3-phenyl-3-tosylaminopropene;SCHEMBL9260649;DTXSID40454008;N-(1-Phenylallyl)-p-toluenesulfonamide

Chemical Property of Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)-

Chemical Property:

• Melting Point: 103 °C(Solv: water (7732-18-5); methanol (67-56-1))
• Boiling Point: 434.4±55.0 °C(Predicted)
• PSA: 54.55000
• Density: 1.168±0.06 g/cm3(Predicted)
• LogP: 4.67230
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 287.09799996
• Heavy Atom Count: 20
• Complexity: 399

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)S(=O)(=O)NC(C=C)C2=CC=CC=C2

Technology Process of Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)-

There total 33 articles about Benzenesulfonamide, 4-methyl-N-(1-phenyl-2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(RS,SR)-N-(2,3-dihydroxy-1-phenylpropyl)-4-toluenesulfonamide → 4-methyl-N-(1-phenyl-allyl)-benzenesulfonamide (58567-43-4)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In toluene; for 2h; Heating;

DOI:10.1021/jo035496s

Reference yield: 94.0%

C23H24N2O4S3 (58647-49-7) → 4-methyl-N-(1-phenyl-allyl)-benzenesulfonamide (58567-43-4)

Guidance literature:

With benzyl tri-n-butylammonium bromide; sodium sulfite; In 1,2-dimethoxyethane; for 24h;

Reference yield: 92.0%

vinylmagnesium chloride (3536-96-7) + phenyl N-tosyl imine (51608-60-7) → 4-methyl-N-(1-phenyl-allyl)-benzenesulfonamide (58567-43-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 20 ℃; for 12h;

DOI:10.1021/ol048161l

upstream raw materials:

benzenesulfenyl-(1-phenyl-allyl)-(toluene-4-sulfonyl)-amine

C₂₃H₂₄N₂O₄S₃

1-phenyl-3-phenylseleno-1-propene

chloroamine-T

Downstream raw materials:

N-(1-methoxy-2-phenylallyl)-N-(1-phenylallyl)-4-methylbenzenesulfonamide

N-(2-oxo-1-phenyl-propyl)-4-methyl-benzenosulfonamide

4-methyl-N-(1-phenylallyl)-N-(prop-2-yn-1-yl)benzenesulfonamide

(E)-N-(1,3-diphenylallyl)-4-methylbenzenesulfonamide