1-Oxa-4,7,10-triazacyclododecane, 4,7,10-tris[(4-methylphenyl)sulfonyl]-

Base Information

Chemical Name:1-Oxa-4,7,10-triazacyclododecane, 4,7,10-tris[(4-methylphenyl)sulfonyl]-
CAS No.:60147-28-6
Molecular Formula:C29H37N3O7S3
Molecular Weight:635.827
Hs Code.:

Synonyms:N,N',N''-tritosyl-1-oxa-4,7,10-triazacyclododecane;4,7,10-Tritosyl-1-oxa-4,7,10-triazacyclodecan;4,7,10-tris-(toluene-4-sulfonyl)-1-oxa-4,7,10-triaza-cyclododecane;1,4,7-triaza-10-oxa-1,4,7-tritosylcyclododecane;4,7,10-tris(p-tolylsulfonyl)-1-oxa-4,7,10-triazacyclododecane;

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Chemical Property of 1-Oxa-4,7,10-triazacyclododecane, 4,7,10-tris[(4-methylphenyl)sulfonyl]-

Chemical Property:

PSA：146.51000
LogP:6.07060

Purity/Quality:

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Technology Process of 1-Oxa-4,7,10-triazacyclododecane, 4,7,10-tris[(4-methylphenyl)sulfonyl]-

There total 5 articles about 1-Oxa-4,7,10-triazacyclododecane, 4,7,10-tris[(4-methylphenyl)sulfonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 5414-19-7
1,1'-oxybis(2-bromo-ethane)

: 56187-04-3
1,4,7-tritosyl-1,4,7-triazaheptane

: 60147-28-6
4,7,10-tris(p-tolylsulphonyl)-1-oxa-4,7,10-triazacyclododecane

Guidance literature:: With lithium hydroxide; tetra-(n-butyl)ammonium iodide; In toluene; for 10h; Heating;

Reference yield: 86.0%

: 56187-04-3
1,4,7-tritosyl-1,4,7-triazaheptane

: 7460-82-4
diethylene glycol ditosylate

: 60147-28-6
4,7,10-tris(p-tolylsulphonyl)-1-oxa-4,7,10-triazacyclododecane

Guidance literature:: 1,4,7-tritosyl-1,4,7-triazaheptane; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃;

diethylene glycol ditosylate; In N,N-dimethyl-formamide; at 70 - 120 ℃; for 16.5h;

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 60147-28-6
4,7,10-tris(p-tolylsulphonyl)-1-oxa-4,7,10-triazacyclododecane

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / pyridine / 5 h / 50 °C

2: 1.) sodium / 1.) CH₃OH, reflux, 2 h, 2.) DMF, 80 deg C, 1 h

With sodium; In pyridine;
DOI:10.1021/ja00387a030