(2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane

Base Information

Chemical Name:(2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane
CAS No.:61102-87-2
Molecular Formula:C18H14ClOP
Molecular Weight:312.735
Hs Code.:
DSSTox Substance ID:DTXSID70522800
Wikidata:Q82388398

Synonyms:61102-87-2;(2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane;DTXSID70522800

Suppliers and Price of (2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane

Chemical Property:

XLogP3:4.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:312.0470798
Heavy Atom Count:21
Complexity:349

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(=O)(C2=CC=CC=C2)C3=CC=CC=C3Cl

Technology Process of (2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane

There total 8 articles about (2-Chlorophenyl)(oxo)diphenyl-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 694-80-4
2-bromo-1-chlorobenzene

: 4559-70-0
Diphenylphosphine oxide

: 61102-87-2
1-bromo-4-(2-bromobenzyloxy)-2-(diphenylphosphinoyl)benzene

Guidance literature:: With nickel(II) chloride hexahydrate; cadmium(II) sulphide; triethylamine; 4,4'-di-tert-butyl-2,2'-bipyridine; In N,N-dimethyl acetamide; at 55 ℃; Irradiation;
DOI:10.1016/S1872-2067(19)63379-6

Reference yield: 63.0%

: 4559-70-0
Diphenylphosphine oxide

: 118-91-2
ortho-chlorobenzoic acid

: 61102-87-2
1-bromo-4-(2-bromobenzyloxy)-2-(diphenylphosphinoyl)benzene

Guidance literature:: With di-tert-butyl dicarbonate; N,N-dimethyl-cyclohexanamine; 1,3-bis-(diphenylphosphino)propane; palladium diacetate; In 1,4-dioxane; at 105 ℃; for 18h; Schlenk technique; Inert atmosphere; Glovebox;

Reference yield: 12.0%

: 1956-97-4
2-chlorobenzenediazonium tetrafluoroborate

: 4559-70-0
Diphenylphosphine oxide

: 61102-87-2
1-bromo-4-(2-bromobenzyloxy)-2-(diphenylphosphinoyl)benzene

Guidance literature:: With palladium diacetate; caesium carbonate; potassium iodide; In acetonitrile; at 20 - 80 ℃; Inert atmosphere;
DOI:10.1039/c0ob00243g