1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene

Base Information

• Chemical Name: 1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene
• CAS No.: 61539-61-5
• Molecular Formula: C9H18O3Si
• Molecular Weight: 202.32300
• DSSTox Substance ID: DTXSID30452578
• Nikkaji Number: J1.189.629D
• Mol file: 61539-61-5.mol

Synonyms:61539-61-5;1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene;4,4-dimethoxybuta-1,3-dien-2-yloxy(trimethyl)silane;Silane, [(3,3-dimethoxy-1-methylene-2-propenyl)oxy]trimethyl-;SCHEMBL9510313;DTXSID30452578;(4,4-dimethoxybuta-1,3-dien-2-yloxy)trimethylsilane;[(4,4-Dimethoxybuta-1,3-dien-2-yl)oxy](trimethyl)silane;[(4,4-DIMETHOXYBUTA-1,3-DIEN-2-YL)OXY]TRIMETHYLSILANE

Chemical Property of 1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene

Chemical Property:

• PSA: 27.69000
• LogP: 2.48580
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 202.10252097
• Heavy Atom Count: 13
• Complexity: 197

Purity/Quality:

1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC(=CC(=C)O[Si](C)(C)C)OC
• Uses: 3-(Trimethylsilyloxy)-1,1-dimethoxy-1,3-butadiene has a wide variety of applications in synthetic chemistry. One example of its applications is its use as a reagent in the synthesis of Lasiodiplodin, a potent antileukemic macrolide.

Technology Process of 1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene

There total 1 articles about 1,1-Dimethoxy-3-(trimethylsiloxy)-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

chloro-trimethyl-silane (75-77-4) + 4,4-dimethoxy-3-buten-2-one (50473-61-5) → 1,1-dimethoxy-3-trimethylsilyloxy-1,3-butadiene (61539-61-5)

Guidance literature:

With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1016/S0040-4020(03)00291-6

Reference yield: 90.0%

1,1-dimethoxy-3-trimethylsilyloxy-1,3-butadiene (61539-61-5) + 2-(methylsulfinyl)naphthoquinone → xanthopurpurin-1-methylether (28504-24-7)

Guidance literature:

In tetrachloromethane; Ambient temperature;

DOI:10.1021/jo00351a030

Reference yield: 85.0%

1,1-dimethoxy-3-trimethylsilyloxy-1,3-butadiene (61539-61-5) + benzaldehyde (100-52-7) → 6-methoxy-2-phenyl-2,3-dihydropyran-4-onen (88083-77-6)

Guidance literature:

Eu(fod)3; In dichloromethane; for 48h; Ambient temperature;

DOI:10.1016/S0040-4039(01)80241-0

upstream raw materials:

chloro-trimethyl-silane

4,4-dimethoxy-3-buten-2-one

Downstream raw materials:

methyl (5-hydroxy-3-methoxy-2-methoxycarbonylphenyl)acetate

4-Hydroxy-2-methoxy-6-oct-7-enyl-benzoic acid methyl ester

2-chloro-5,7-dimethoxy-1,4-naphthoquinone

3-Methoxy-4-acetylcyclohex-2-en-1-on

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