[3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone

Base Information

Chemical Name:[3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone
CAS No.:61840-97-9
Molecular Formula:C15H11NO4
Molecular Weight:269.257
Hs Code.:
DSSTox Substance ID:DTXSID50465887
Nikkaji Number:J1.228.603A
Wikidata:Q82292178

Synonyms:CTK2D1435;DTXSID50465887;61840-97-9;[3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone

Suppliers and Price of [3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of [3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:269.06880783
Heavy Atom Count:20
Complexity:378

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C(=O)C2C(O2)C3=CC=C(C=C3)[N+](=O)[O-]
Isomeric SMILES:C1=CC=C(C=C1)C(=O)[C@H]2[C@@H](O2)C3=CC=C(C=C3)[N+](=O)[O-]

Technology Process of [3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone

There total 16 articles about [3-(4-Nitro-phenyl)-oxiranyl]-phenyl-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2960-55-6
(E)-3-(4-nitrophenyl)-1-phenylprop-2-en-1-one

: 61840-97-9
(2R,3S)-[3-(p-nitrophenyl)oxiran-2-yl]phenylmethanone

Guidance literature:: With N-(2',3',4'-trifluoro)benzyl-O⁽⁹⁾-allylhydrocinchoninium bromide; sodium hypochlorite; In water; toluene; at 0 ℃; for 40h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tetlet.2010.08.056

Reference yield: 94.0%

: 555-16-8
4-nitrobenzaldehdye

: 98-86-2
acetophenone

: 61840-97-9
(2R,3S)-[3-(p-nitrophenyl)oxiran-2-yl]phenylmethanone

Guidance literature:: 4-nitrobenzaldehdye; acetophenone; at 60 ℃; for 3h;

With tetrabutylammomium bromide; dihydrogen peroxide; sodium hydroxide; In toluene; at 20 ℃; for 1.5h; enantioselective reaction;
DOI:10.1016/j.jcat.2015.11.020

Reference yield: 92.0%

: 1222-98-6
4-nitrochalcone

: 61840-97-9
(2R,3S)-[3-(p-nitrophenyl)oxiran-2-yl]phenylmethanone

Guidance literature:: With C₅₈H₆₄N₄O₄S⁽²⁺⁾*2Br^(1-); dihydrogen peroxide; caesium carbonate; In water; toluene; at 20 ℃; for 4.5h; Reagent/catalyst; enantioselective reaction;
DOI:10.1016/j.molcata.2015.08.016