Bis(trimethylsilyl)(phenylthio)methane

Base Information

Chemical Name:Bis(trimethylsilyl)(phenylthio)methane
CAS No.:62761-90-4
Molecular Formula:C13H24SSi2
Molecular Weight:268.571
Hs Code.:
DSSTox Substance ID:DTXSID70451848
Nikkaji Number:J305.899I
Wikidata:Q82272109

Synonyms:62761-90-4;Bis(trimethylsilyl)(phenylthio)methane;AGN-PC-0NEEC3;DTXSID70451848;(phenylthio)bis(trimethylsilyl)methane

Suppliers and Price of Bis(trimethylsilyl)(phenylthio)methane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Bis(trimethylsilyl)(phenylthio)methane

Chemical Property:

Boiling Point:137-140 °C(Press: 2 Torr)
PSA：25.30000
Density:0.92±0.1 g/cm3(Predicted)
LogP:5.32200
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:268.11372501
Heavy Atom Count:16
Complexity:195

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C([Si](C)(C)C)SC1=CC=CC=C1
Physical properties bp 88 °C/0.16 mmHg.
Uses Phenylthiobis(trimethylsilyl)methane can be used in formation of vinylsilanes and as a methoxycarbonyl anion equivalent.

Technology Process of Bis(trimethylsilyl)(phenylthio)methane

There total 2 articles about Bis(trimethylsilyl)(phenylthio)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 75-77-4
chloro-trimethyl-silane

: 30536-77-7,167469-49-0
<(phenylthio)(trimethylsilyl)methyl>lithium

: 62761-90-4
α,α-bis(trimethylsilyl)methylphenyl sulfide

Guidance literature:: In tetrahydrofuran;
DOI:10.1016/S0040-4039(01)90557-X

Reference yield:

: 100-68-5
methyl-phenyl-thioether

: 62761-90-4
α,α-bis(trimethylsilyl)methylphenyl sulfide

Guidance literature:: Multi-step reaction with 2 steps

1: (i) nBuLi, Me₂NCH₂CH₂NMe₂, (ii) /BRN= 1209232/

2: (i) nBuLi, (ii) /BRN= 1209232/

Reference yield: 89.0%

: 119-61-9
benzophenone

: 62761-90-4
α,α-bis(trimethylsilyl)methylphenyl sulfide

: 13112-46-4
2,2-diphenyl-1-phenylthioethene

Guidance literature:: With molecular sieve; tris(dimethylamino)sulfonium trimethylsilyldifluoride; In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1021/jo00295a047