Trimethyl(6-methylcyclohex-1-en-1-yl)silane

Base Information

• Chemical Name: Trimethyl(6-methylcyclohex-1-en-1-yl)silane
• CAS No.: 63031-68-5
• Molecular Formula: C10H20Si
• Molecular Weight: 168.354
• DSSTox Substance ID: DTXSID80500255
• Mol file: 63031-68-5.mol

Synonyms:63031-68-5;Trimethyl(6-methylcyclohex-1-en-1-yl)silane;DTXSID80500255;AKOS024330147;TRIMETHYL(6-METHYL-1-CYCLOHEXEN-1-YL)SILANE

Chemical Property of Trimethyl(6-methylcyclohex-1-en-1-yl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 168.133427172
• Heavy Atom Count: 11
• Complexity: 162

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CCCC=C1[Si](C)(C)C

Technology Process of Trimethyl(6-methylcyclohex-1-en-1-yl)silane

There total 3 articles about Trimethyl(6-methylcyclohex-1-en-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methylcyclohexanone (583-60-8) → 2-(trimethylsilyl)-3-methylcyclohexene (63031-68-5)

Guidance literature:

Multistep reaction;

DOI:10.1021/ja00509a084

Reference yield:

chloro-trimethyl-silane (75-77-4) + 2-methylcyclohexanone benzenesulfonylhydrazone (56975-76-9) → 2-(trimethylsilyl)-3-methylcyclohexene (63031-68-5)

Guidance literature:

Multistep reaction; (i) alkyllithium, Me₂NCH₂CH₂NMe₂, (ii) /BRN= 1209232/;

DOI:10.1021/jo00402a043

Reference yield:

chloro-trimethyl-silane (75-77-4) + 4-methyl-N'-(2-methylcyclohexylidene)benzenesulfonohydrazide (52826-41-2) → 2-(trimethylsilyl)-3-methylcyclohexene (63031-68-5)

Guidance literature:

Multistep reaction; (i) nBuLi, Me₂NCH₂CH₂NMe₂, (ii) /BRN= 1209232/;

DOI:10.1016/S0040-4039(01)92576-6

upstream raw materials:

chloro-trimethyl-silane

4-methyl-N'-(2-methylcyclohexylidene)benzenesulfonohydrazide

2-methylcyclohexanone benzenesulfonylhydrazone

2-Methylcyclohexanone

Downstream raw materials:

3-Methylcyclohexanone

2-(trimethylsilyl)-3-methylcyclohexanone

4-(6-Methylcyclohexen-1-yl)butan-2-one

3-methyl-cis-2-(trimethylsilyl)cyclohexanol