[(1-Methoxyoctan-2-YL)selanyl]benzene

Base Information

• Chemical Name: [(1-Methoxyoctan-2-YL)selanyl]benzene
• CAS No.: 63603-32-7
• Molecular Formula: C15H24OSe
• Molecular Weight: 299.315
• DSSTox Substance ID: DTXSID50560023
• Nikkaji Number: J371.438A
• Mol file: 63603-32-7.mol

Synonyms:63603-32-7;[(1-METHOXYOCTAN-2-YL)SELANYL]BENZENE;DTXSID50560023

Chemical Property of [(1-Methoxyoctan-2-YL)selanyl]benzene

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 300.09924
• Heavy Atom Count: 17
• Complexity: 166

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC(COC)[Se]C1=CC=CC=C1

Technology Process of [(1-Methoxyoctan-2-YL)selanyl]benzene

There total 3 articles about [(1-Methoxyoctan-2-YL)selanyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

methanol (67-56-1) + oct-1-ene (111-66-0,25068-25-1) + diphenyl diselenide (1666-13-3) → methyl 1-phenylselenenyl-2-octyl ether (63603-31-6) + (1-methoxyoctan-2-yl)(phenyl)selane (63603-32-7)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; at 30 ℃;

DOI:10.1055/s-2001-18091

Reference yield:

methanol (67-56-1) + phenyl selenocyanate (2179-79-5) + oct-1-ene (111-66-0,25068-25-1) → methyl 1-phenylselenenyl-2-octyl ether (63603-31-6) + (1-methoxyoctan-2-yl)(phenyl)selane (63603-32-7)

Guidance literature:

copper dichloride; at 65 ℃; for 0.5h; Mechanism; Product distribution; other times; other temperatures;

DOI:10.1021/jo01298a039

Reference yield:

→ (1-methoxyoctan-2-yl)(phenyl)selane (63603-32-7)

Guidance literature:

Oct-1-en, C6H5SeCN, CuCl2, in CH3OH, 65grad, 0.5 h;

DOI:10.1039/c39770000166

upstream raw materials:

methanol

phenyl selenocyanate

oct-1-ene

diphenyl diselenide