p-Methoxybenzyl phenyl carbonate

Base Information

• Chemical Name: p-Methoxybenzyl phenyl carbonate
• CAS No.: 31558-46-0
• Molecular Formula: C15H14 O4
• Molecular Weight: 258.274
• European Community (EC) Number: 250-699-3
• UNII: 74U9IS65VU
• DSSTox Substance ID: DTXSID10185458
• Nikkaji Number: J278.146H
• Wikidata: Q83056480
• Mol file: 31558-46-0.mol

Synonyms:p-Methoxybenzyl phenyl carbonate;31558-46-0;4-methoxybenzyl phenyl carbonate;(4-methoxyphenyl)methyl phenyl carbonate;74U9IS65VU;EINECS 250-699-3;Carbonic Acid 4-Methoxy-Benzyl Ester Phenyl Ester;UNII-74U9IS65VU;SCHEMBL9662594;DTXSID10185458;AKOS024332941;Carbonic acid (4-methoxyphenyl)methylphenyl ester

Chemical Property of p-Methoxybenzyl phenyl carbonate

Chemical Property:

• Vapor Pressure: 2.21E-06mmHg at 25°C
• Boiling Point: 392.9°Cat760mmHg
• Flash Point: 174.4°C
• Density: 1.184g/cm³
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 258.08920892
• Heavy Atom Count: 19
• Complexity: 265

Purity/Quality:

99% ^*data from raw suppliers

4-METHOXYBENZYL PHENYL CARBONATE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)COC(=O)OC2=CC=CC=C2

Technology Process of p-Methoxybenzyl phenyl carbonate

There total 1 articles about p-Methoxybenzyl phenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenyl chloroformate (1885-14-9) + 4-Methoxybenzyl alcohol (105-13-5) → 4-methoxybenzyl phenyl carbonate (31558-46-0)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 20 ℃; for 20.1667h;

DOI:10.1021/ol800548t

Reference yield: 97.0%

4-methoxybenzyl phenyl carbonate (31558-46-0) → 4-methoxybenzyl phenyl ether (19962-28-8)

Guidance literature:

With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether; In toluene; at 60 ℃; for 3.08333h; Inert atmosphere;

DOI:10.1021/ol800548t

Reference yield: 80.0%

4-methoxybenzyl phenyl carbonate (31558-46-0) + N,N-dimethylethylenediamine (108-00-9) → 4-methoxybenzyl 2-(dimethylamino)ethylcarbamate (1358795-44-4)

Guidance literature:

In benzene; at 80 ℃;

DOI:10.1007/s10870-011-9991-z

upstream raw materials:

phenyl chloroformate

4-Methoxybenzyl alcohol

Downstream raw materials:

4-methoxybenzyl hydrazinecarboxylate

4-methoxybenzyl phenyl ether

N-(4-methoxy-benzyloxycarbonyl)-glycine

N-<<(p-methoxybenzyl)oxy>carbonyl>-L-serine

Refernces

• 1、 Reddy, Golipalli Ramana,Avadhani, Anusha S.,Rajaram, Sridhar. "Activation of Benzyl Aryl Carbonates: The Role of Cation-π Interactions". . p. 4134 - 4141. Retrieved 2016/06/09.