Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane

Base Information

Chemical Name:Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane
CAS No.:66128-13-0
Molecular Formula:C15H19OPSi
Molecular Weight:274.37000
Hs Code.:
DSSTox Substance ID:DTXSID60556114
Wikidata:Q82437593

Synonyms:66128-13-0;Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane;DTXSID60556114

Suppliers and Price of Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DIPHENYL(TRIMETHYLSILYL)PHOSPHINE OXIDE 95.00%
5MG
$ 497.94

Total 2 raw suppliers

Chemical Property of Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane

Chemical Property:

PSA：26.88000
LogP:3.83540
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:274.09427876
Heavy Atom Count:18
Complexity:287

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

DIPHENYL(TRIMETHYLSILYL)PHOSPHINE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)P(=O)(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane

There total 5 articles about Oxo(diphenyl)(trimethylsilyl)-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 75-77-4
chloro-trimethyl-silane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 66128-13-0
trimethylsilyldiphenylphosphine oxide

Guidance literature:: With nickel tetrafluoroborate; lithium perchlorate; In acetonitrile; electrolysis;

Reference yield:

: 17154-34-6
(trimethylsilyl)diphenylphosphine

: 2096-83-5
tetraphenyldiphosphine oxide

: 66128-13-0
trimethylsilyldiphenylphosphine oxide

: 1101-41-3
Tetraphenyldiphosphin

: 829-85-6
diphenylphosphane

Guidance literature:: With indium(III) chloride; water; In tetrahydrofuran; Inert atmosphere; Glovebox; Schlenk technique; Reflux;
DOI:10.1016/j.ica.2021.120772

Reference yield:

: 603-35-0
triphenylphosphine

: 2096-83-5
tetraphenyldiphosphine oxide

: 66128-13-0
trimethylsilyldiphenylphosphine oxide

: 1101-41-3
Tetraphenyldiphosphin

: 829-85-6
diphenylphosphane

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium / Inert atmosphere; Schlenk technique; Glovebox

1.2: Inert atmosphere; Schlenk technique; Glovebox

2.1: indium(III) chloride; water / tetrahydrofuran / Inert atmosphere; Glovebox; Schlenk technique; Reflux

With indium(III) chloride; water; lithium; In tetrahydrofuran;
DOI:10.1016/j.ica.2021.120772