benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

Base Information

Chemical Name:benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)
CAS No.:797057-62-6
Molecular Formula:C₁₉H₂₄N₂O₂Pt
Molecular Weight:507.492
Hs Code.:

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Chemical Property of benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

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Technology Process of benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

There total 3 articles about benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 663164-11-2
chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

: 532-31-0
silver benzoate

: 797057-62-6
benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

Guidance literature:: In acetone; under Ar; soln. of Pt complex in acetone added to Ag salt (molar ratio 1:1); stirred overnight in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;
DOI:10.1021/om040061w

Reference yield:

: 797057-65-9
cis-methylbis(benzoato)(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(IV)

: 797057-62-6
benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

Guidance literature:: In ⁽²⁾H₈-toluene; byproducts: methyl benzoate; under Ar; soln. of Pt complex in toluene-d8 heated at 50°C; not isolated; monitored by (1)H NMR spectra; Kinetics;
DOI:10.1021/om040061w

Reference yield:

: 95532-51-7
4-tolyl(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

: 94-36-0
dibenzoyl peroxide

: 797057-64-8
cis-4-tolylbis(benzoato)(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(IV)

: 797057-62-6
benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

Guidance literature:: In [⁽²⁾H₆]acetone; under Ar; Pt complex reacted with (PhCO2)2 in acetone-d6 at 25°C; not isolated; detd. by (1)H NMR spectra;
DOI:10.1021/om040061w