Benzene, (4-methoxy-3-butenyl)-, (Z)-

Base Information

• Chemical Name: Benzene, (4-methoxy-3-butenyl)-, (Z)-
• CAS No.: 69485-50-3
• Molecular Formula: C11H14O
• Molecular Weight: 162.22800
• Mol file: 69485-50-3.mol

Synonyms:cis-1-methoxy-4-phenyl butene;((Z)-4-Methoxy-but-3-enyl)-benzene;(Z)-1-Methoxy-4-phenyl-1-butene;(4-methoxybut-3-enyl)benzene;

Chemical Property of Benzene, (4-methoxy-3-butenyl)-, (Z)-

Chemical Property:

• PSA: 9.23000
• LogP: 2.77930

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, (4-methoxy-3-butenyl)-, (Z)-

There total 3 articles about Benzene, (4-methoxy-3-butenyl)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

Methyl formate (107-31-3) + C21H10BF10(1-)*Li(1+)*C9H19N → 3-benzyl propionaldehyde (18328-11-5) + (Z)-(4-methoxybut-3-en-1-yl)benzene (69485-50-3)

Guidance literature:

at 20 ℃; for 0.333333h;

DOI:10.1039/c7ob01591g

Reference yield:

3-phenyl-propionaldehyde (104-53-0) + (methoxymethyl)triphenylphosphonium chloride (4009-98-7) → (Z)-(4-methoxybut-3-en-1-yl)benzene (69485-50-3) + (E)-1-Methoxy-4-phenyl-1-butene (69485-51-4)

Guidance literature:

(methoxymethyl)triphenylphosphonium chloride; With potassium tert-butylate; In tetrahydrofuran; at 23 ℃; for 0.75h;

3-phenyl-propionaldehyde; In tetrahydrofuran; at 23 ℃; for 2h; Overall yield = 92%;

Reference yield:

3-phenyl-propionaldehyde (104-53-0) + (methoxymethyl)triphenylphosphonium hydrochloride → (Z)-(4-methoxybut-3-en-1-yl)benzene (69485-50-3) + (E)-1-Methoxy-4-phenyl-1-butene (69485-51-4)

Guidance literature:

(methoxymethyl)triphenylphosphonium hydrochloride; With potassium tert-butylate; In tetrahydrofuran; at 23 ℃; for 0.75h;

3-phenyl-propionaldehyde; In tetrahydrofuran; at 23 ℃; for 2h; Overall yield = 92 %;

DOI:10.1021/ja512073m

upstream raw materials:

3-phenyl-propionaldehyde

(methoxymethyl)triphenylphosphonium chloride

Methyl formate