Technology Process of N,N-Diphenylpyren-1-amine
There total 6 articles about N,N-Diphenylpyren-1-amine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1-bromopyrene; diphenylamine;
With
tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate;
Glovebox;
Inert atmosphere;
With
cyclo-octa-1,5-diene;
for 1.65h;
Inert atmosphere;
- Guidance literature:
-
With
2,2,6,6-tetramethylpiperidinyl-lithium;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
1.) room temperature, 2 h, 2.) reflux, 27 h;
DOI:10.1021/ja00401a026
- Guidance literature:
-
Multi-step reaction with 2 steps
1: N-Bromosuccinimide / N,N-dimethyl-formamide / 24 h / 20 °C
2: palladium diacetate; tri-tert-butyl phosphine; caesium carbonate / o-xylene / 12 h / 160 °C
With
N-Bromosuccinimide; tri-tert-butyl phosphine; palladium diacetate; caesium carbonate;
In
o-xylene; N,N-dimethyl-formamide;
2: |Buchwald-Hartwig Coupling;
DOI:10.1016/j.molstruc.2012.09.028
