Stannane, trimethyl[(1E)-2-phenylethenyl]-

Base Information

• Chemical Name: Stannane, trimethyl[(1E)-2-phenylethenyl]-
• CAS No.: 7422-28-8
• Molecular Formula: C₁₁H₁₆Sn
• Molecular Weight: 266.958
• DSSTox Substance ID: DTXSID20478060
• Mol file: 7422-28-8.mol

Synonyms:Stannane, trimethyl[(1E)-2-phenylethenyl]-;7422-28-8;DTXSID20478060

Chemical Property of Stannane, trimethyl[(1E)-2-phenylethenyl]-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 268.027403
• Heavy Atom Count: 12
• Complexity: 147

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)C=CC1=CC=CC=C1

Technology Process of Stannane, trimethyl[(1E)-2-phenylethenyl]-

There total 18 articles about Stannane, trimethyl[(1E)-2-phenylethenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

lithium trimethylstannyl (17946-71-3) + phenylacetylene (536-74-3) → 1-(trimethylstannyl)-2-phenylethyne (1199-95-7) + trimethylstannylstyrene (7422-28-8,17421-57-7,50849-52-0)

Guidance literature:

In ammonia; byproducts: LiH; (Ar), stirred 2 h at -33°C; diluted (pentane), filtered in inert atm., solvent removed (reduced pressure), gas-liq. chromy.; PMR, ESR;

Reference yield: 79.0%

potassium trimethylstannate (38423-82-4) + phenylacetylene (536-74-3) → 1-(trimethylstannyl)-2-phenylethyne (1199-95-7) + trimethylstannylstyrene (7422-28-8,17421-57-7,50849-52-0)

Guidance literature:

In ammonia; (Ar), stirred 2 h at -33°C; diluted (pentane), filtered in inert atm., solvent removed (reduced pressure), gas-liq. chromy.; PMR, ESR;

Reference yield: 75.0%

trimethylstannyl sodium (16643-09-7) + phenylacetylene (536-74-3) → 1-(trimethylstannyl)-2-phenylethyne (1199-95-7) + trimethylstannylstyrene (7422-28-8,17421-57-7,50849-52-0)

Guidance literature:

In ammonia; (Ar), stirred 2 h at -33°C; diluted (pentane), filtered in inert atm., solvent removed (reduced pressure), gas-liq. chromy.; PMR, ESR;

upstream raw materials:

trimethylstannane

phenylacetylene

[(E)-2-bromoethenyl]benzene

trimethyltin(IV)chloride

Downstream raw materials:

nitrostyrene

(Z)-nitrostyrene

(E)-2-phenylethenyl(trimethyl)stannane

2-acetyl-2-<(E)-styryl>-3,4-dihydronaphthalen-1(2H)-one