Tributyl[(4-methoxyphenyl)methyl]stannane

Base Information

Chemical Name:Tributyl[(4-methoxyphenyl)methyl]stannane
CAS No.:74260-40-5
Molecular Formula:C20H36OSn
Molecular Weight:411.215
Hs Code.:
DSSTox Substance ID:DTXSID40524755

Synonyms:74260-40-5;TRIBUTYL[(4-METHOXYPHENYL)METHYL]STANNANE;SCHEMBL6785733;DTXSID40524755

Suppliers and Price of Tributyl[(4-methoxyphenyl)methyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tributyl[(4-methoxyphenyl)methyl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:12
Exact Mass:412.178818
Heavy Atom Count:22
Complexity:237

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)CC1=CC=C(C=C1)OC

Technology Process of Tributyl[(4-methoxyphenyl)methyl]stannane

There total 3 articles about Tributyl[(4-methoxyphenyl)methyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 19350-72-2
N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide

: 688-73-3
tri-n-butyl-tin hydride

: 74260-40-5
4-methoxybenzyltri-n-butylstannane

Guidance literature:: N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide; With tetrabutyl-ammonium chloride; sodium hydride; In toluene; mineral oil; at 20 ℃; for 0.166667h; Inert atmosphere;

tri-n-butyl-tin hydride; In toluene; mineral oil; at 110 ℃; for 6h;

Reference yield: 35.0%

: 813-19-4
bis(tri-n-butyltin)

: 824-94-2
p-methoxybenzyl chloride

: 74260-40-5
4-methoxybenzyltri-n-butylstannane

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; byproducts: (C4H9)3SnCl, (p-MeOC6H4CH2)2; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;
DOI:10.1016/S0022-328X(00)84615-X

Reference yield:

: 123-11-5
4-methoxy-benzaldehyde

: 74260-40-5
4-methoxybenzyltri-n-butylstannane

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene / 1 h / 80 °C / Inert atmosphere; Schlenk technique; Sealed tube

2.1: sodium hydride; tetrabutyl-ammonium chloride / toluene / 0.17 h / 20 °C / Inert atmosphere; Schlenk technique

2.2: 6 h / 110 °C / Inert atmosphere; Schlenk technique

With tetrabutyl-ammonium chloride; sodium hydride; In toluene;
DOI:10.1021/acs.joc.6b02639