N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine

Base Information

• Chemical Name: N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine
• CAS No.: 74400-91-2
• Molecular Formula: C12H31N4P
• Molecular Weight: 262.379
• DSSTox Substance ID: DTXSID90397118
• Nikkaji Number: J2.101.545H
• Wikidata: Q82198181
• Mol file: 74400-91-2.mol

Synonyms:74400-91-2;Phosphorimidic triamide, N,N,N',N',N'',N''-hexaethyl-;N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine;[Bis(diethylamino)(imino)-phosphanyl]diethylamine;SCHEMBL8030594;DTXSID90397118;HMS1786B08;AKOS026676606;P,P,P-Tris(diethylamino)phosphine imide;[bis(diethylamino)(imino)-??-phosphanyl]diethylamine;Z56857114;F8880-8626;T0510-9446

Chemical Property of N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine

Chemical Property:

• Boiling Point: 82-83 °C(Press: 0.04 Torr)
• PSA: 43.38000
• Density: 0.97±0.1 g/cm3(Predicted)
• LogP: 3.63650
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 262.22863400
• Heavy Atom Count: 17
• Complexity: 195

Purity/Quality:

[Bis(diethylamino)(imino)-phosphanyl]diethylamine 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)P(=N)(N(CC)CC)N(CC)CC

Technology Process of N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine

There total 7 articles about N-[bis(diethylamino)phosphinimyl]-N-ethylethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tris(N,N-diethylamino)aminophosphonium chloride → N,N,N',N',N'',N''-hexaethylphosphonimidic triamide (74400-91-2)

Guidance literature:

With sodium hydroxide; In water; at 20 ℃; for 1h;

Reference yield: 88.0%

1-amino-naphthalene (134-32-7) + azidotris(diethylamino)phosphonium bromide → 1-azidonaphthalene (6921-40-0) + N,N,N',N',N'',N''-hexaethylphosphonimidic triamide (74400-91-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.75h;

DOI:10.1016/S0040-4039(02)01444-2

Reference yield: 87.0%

diethylamine (109-89-7) → N,N,N',N',N'',N''-hexaethylphosphonimidic triamide (74400-91-2)

Guidance literature:

diethylamine; With phosphorus pentachloride; In dichloromethane; at -78 - 20 ℃;

With ammonia; In dichloromethane; at -20 ℃; for 0.833333h;

With potassium tert-butylate; In methanol; at -20 - 20 ℃;

DOI:10.1002/anie.201908589

upstream raw materials:

hexaethyl-N'''-(phenylsulfonyl)phosphorimidic triamide

N,N,N',N',N'',N''-hexaethylphosphorohydrazonic triamide

1-amino-naphthalene

chlorotris(diethylamino)phosphonium chloride

Downstream raw materials:

tetrakis(diethylamino)phosphonium bromide

hexaethylphosphoric triamide