3-Bromo-4'-methoxybiphenyl

Base Information

• Chemical Name: 3-Bromo-4'-methoxybiphenyl
• CAS No.: 74447-72-6
• Molecular Formula: C13H11BrO
• Molecular Weight: 263.13000
• European Community (EC) Number: 801-919-7

Synonyms:3-Bromo-4'-methoxybiphenyl;3-bromo-4'-methoxy-1,1'-biphenyl;74447-72-6;1-bromo-3-(4-methoxyphenyl)benzene;SCHEMBL1181012;UPKCIOJEMVKOAU-UHFFFAOYSA-N;FS-6185

Chemical Property of 3-Bromo-4'-methoxybiphenyl

Chemical Property:

• PSA: 9.23000
• LogP: 4.12470
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 261.99933
• Heavy Atom Count: 15
• Complexity: 187

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C2=CC(=CC=C2)Br

Technology Process of 3-Bromo-4'-methoxybiphenyl

There total 6 articles about 3-Bromo-4'-methoxybiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromobenzene (108-86-1,52753-63-6) + 4-methoxybenzenediazonium tetrafluoroborate (459-64-3) → 4-bromo-4'-methoxylbiphenyl (58743-83-2) + 3-bromo-4'-methoxy-1,1'-biphenyl (74447-72-6) + 2-bromo-4'-methoxy-1,1'-biphenyl (74447-76-0)

Guidance literature:

With pyridine; at 23 ℃; for 18h; Overall yield = 82 percent; Overall yield = 129 mg; Inert atmosphere; Irradiation;

DOI:10.1021/acs.joc.9b00557

Reference yield:

bromobenzene (108-86-1,52753-63-6) + 4-methoxyphenylhydrazine hydrochloride (19501-58-7) → 4-bromo-4'-methoxylbiphenyl (58743-83-2) + 3-bromo-4'-methoxy-1,1'-biphenyl (74447-72-6) + 2-bromo-4'-methoxy-1,1'-biphenyl (74447-76-0)

Guidance literature:

With manganese triacetate; Title compound not separated from byproducts.; Heating;

DOI:10.1039/b105119a

Reference yield:

bromobenzene (108-86-1,52753-63-6) + 4-methoxyphenylboronic acid (5720-07-0) → 4-bromo-4'-methoxylbiphenyl (58743-83-2) + 3-bromo-4'-methoxy-1,1'-biphenyl (74447-72-6) + 2-bromo-4'-methoxy-1,1'-biphenyl (74447-76-0)

Guidance literature:

With manganese triacetate; Further Variations:; Reaction partners; Product distribution; Heating;

DOI:10.1021/jo026466c

upstream raw materials:

bromobenzene

4-methoxyphenylhydrazine hydrochloride

4-methoxyphenylboronic acid

bis(4-methoxyphenyl)iodonium trifluoroacetate

Downstream raw materials:

3-(2-hydroxyadamantan-2-yl)-4'-methoxybiphenyl

3-(2-hydroxyadamantan-2-yl)-4'-hydroxybiphenyl

3-(2-methoxyadamantan-2-yl)-4'-hydroxybiphenyl

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