Synonyms:Manganese(3+) acetate;SCHEMBL19837;JXNCBISRWFPKJU-UHFFFAOYSA-N;NSC112209
99% *data from raw suppliers
There total 42 articles about Manganese(3+) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
Reference yield: 95.0%
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The research focuses on the development of an enantio- and diastereo-selective approach to substituted pyrrolidinones using manganese(III) acetate-mediated alkylation of β-keto esters and β-keto amides. The purpose of this study was to efficiently construct quaternary carbon centers through intermolecular radical addition reactions, utilizing β-keto esters and amides with enol ethers and manganese(III) acetate in the presence of copper(II) acetate. The conclusions drawn from the research indicate that manganese(III) acetate can be effectively used to introduce functionalized side-chains at the α-position of α-substituted β-keto esters and amides, including pyrrolidinones, offering a favorable alternative to traditional base-mediated alkylation methods.
The study investigates the oxidative decarboxylation of arylacetic acids to arylcarbinols using different reagents, with a focus on Mn(III) acetate, Ce(IV) ammonium nitrate, and a combination reagent of Co(III) acetate-Cu(II) acetate. The researchers found that Mn(III) acetate in acetic acid is particularly effective for this reaction, especially with substrates carrying an electron-donating group at the para position of the aromatic ring or when the acid is secondary or tertiary. The study compared the results of using Mn(III) acetate with those of the other reagents, noting that the latter often produced mixtures containing over-oxidation products or products formed via different routes. The study concludes that Mn(III) acetate is superior for the oxidative decarboxylation of arylacetic acids, offering better yields and selectivity compared to the other reagents tested.
The research investigates the oxidation of alkyl substituted 1-(phenylsulfonyl)indolines using manganese(III) acetate. The purpose of the study is to explore the oxidation of these indolines to achieve tandem oxidation of the indoline ring and the C-2 methyl group, or nuclear acetoxylation if there is no alkyl substituent at the C-2 position. Key chemicals used include manganese(III) acetate as the oxidant, alkyl substituted 1-(phenylsulfonyl)indolines as substrates, and acetic acid as a solvent. The study found that when a C-2 methyl group is present, it undergoes selective acetoxylation, yielding C-2 acetoxylated indoles with good yields (53-66%). In cases where there is no C-2 substituent, nuclear acetoxylation occurs, resulting in oxindoles. The addition of bromide ions did not improve the process but led to the formation of brominated products in some instances. The study concludes that manganese(III) acetate can effectively mediate these oxidations, providing a useful method for synthesizing C-2 acetoxylated indoles and oxindoles, with potential applications in the synthesis of natural products containing the indole skeleton.
The research investigates the reaction of various olefins with malonic acid in the presence of manganese(III) acetate (MA) to synthesize substituted 2,7-dioxaspiro[4.4]nonane-1,6-diones and other related compounds. The purpose is to develop a convenient one-step synthesis method for these compounds, which have potential applications in organic chemistry. Key chemicals used include olefins such as 1,1-diphenylethene, 1,1-bis(4-methoxyphenyl)ethene, methylenecyclohexane, 2-phenylpropene, styrene, 1-octene, and cyclohexene, along with malonic acid and manganese(III) acetate. The reactions were carried out in acetic acid, and the products were characterized using techniques like IR spectroscopy, H-NMR spectroscopy, and HPLC. The study concludes that this method provides a straightforward and efficient route to synthesize the target compounds, with yields ranging from 3% to 84% depending on the specific olefin used. The configurations of the products were determined based on H-NMR spectral analyses, and the results showed that the reaction outcomes varied significantly depending on the substituents on the olefins.
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