Dimethyl (2-chlorobenzoyl)phosphonate

Base Information

Chemical Name:Dimethyl (2-chlorobenzoyl)phosphonate
CAS No.:76387-49-0
Molecular Formula:C9H10ClO4P
Molecular Weight:248.603
Hs Code.:
DSSTox Substance ID:DTXSID50505353
Wikidata:Q82360401

Synonyms:76387-49-0;Dimethyl (2-chlorobenzoyl)phosphonate;SCHEMBL11408624;DTXSID50505353

Suppliers and Price of Dimethyl (2-chlorobenzoyl)phosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Dimethyl (2-chlorobenzoyl)phosphonate

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:248.0005235
Heavy Atom Count:15
Complexity:273

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COP(=O)(C(=O)C1=CC=CC=C1Cl)OC

Technology Process of Dimethyl (2-chlorobenzoyl)phosphonate

There total 1 articles about Dimethyl (2-chlorobenzoyl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 609-65-4
o-chlorobenzoyl chloride

: 121-45-9
phosphorous acid trimethyl ester

: 76387-49-0
Dimethyl 2-chlorobenzoylphosphonate

Guidance literature:: In toluene;

Reference yield: 90.0%

: 76387-49-0
Dimethyl 2-chlorobenzoylphosphonate

: 59414-23-2
1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene

: 1293917-94-8
dimethyl (2-(2-chlorophenyl)-4-oxo-3,4-dihydro-2H-pyran-2-yl)phosphonate

Guidance literature:: Dimethyl 2-chlorobenzoylphosphonate; 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene; In toluene; at 100 ℃; for 16h; Inert atmosphere;

With trifluoroacetic acid; In toluene; at 0 ℃;
DOI:10.1016/j.tet.2011.02.007

Reference yield: 77.0%

: 76387-49-0
Dimethyl 2-chlorobenzoylphosphonate

: 75-24-1
trimethylaluminum

: 1307916-28-4
dimethyl (1-(2-chlorophenyl)-1-hydroxyethyl)phosphonate

Guidance literature:: Dimethyl 2-chlorobenzoylphosphonate; trimethylaluminum; In n-heptane; toluene; at 0 ℃; for 0.166667h; Inert atmosphere;

With water; In n-heptane; toluene; Inert atmosphere;
DOI:10.1016/j.tet.2011.03.036