2-Amino-6-methylbiphenyl

Base Information

Chemical Name:2-Amino-6-methylbiphenyl
CAS No.:76472-83-8
Molecular Formula:C13H13N
Molecular Weight:183.24900
Hs Code.:2921499090
Mol file:76472-83-8.mol

Synonyms:6-Amino-2-methyl-biphenyl;[1,1‘-Biphenyl]-2-amine, 6-methyl-;6-methyl-(1,1'-biphenyl)-2-amine;2-amino-6-methylbiphenyl;6-Methyl-biphenyl-2-ylamin;6-methylbiphenyl-2-amine;

Suppliers and Price of 2-Amino-6-methylbiphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-Amino-6-methylbiphenyl

Chemical Property:

Melting Point:43.5°C
Refractive Index:1.6193 (estimate)
Boiling Point:306.94°C (rough estimate)
PSA：26.02000
Density:1.0650 (rough estimate)
LogP:3.82540

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Amino-6-methylbiphenyl

There total 3 articles about 2-Amino-6-methylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.7%

: 620-25-7
N-(3-methylphenyl)hydroxylamine

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 63019-97-6
4-amino-2-methyl-1-phenylbenzene

: 76472-83-8
6-methyl-[1,1'-biphenyl]-2-amine

: 54147-94-3
2-amino-4-methylbiphenyl

: 3-methyl-4-((trifluoromethanesulfonyl)oxy)aniline

Guidance literature:: With trifluorormethanesulfonic acid; at 5 ℃; for 0.5h;
DOI:10.1021/ja00393a025

Reference yield:

: 20222-31-5
N-trityl-m-toluidine

: 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 76472-83-8
6-methyl-[1,1'-biphenyl]-2-amine

: 54147-94-3
2-amino-4-methylbiphenyl

Guidance literature:: N-trityl-m-toluidine; 2-(trimethylsilyl)phenyl trifluoromethanesulfonate; With cesium fluoride; In toluene; acetonitrile; at 110 ℃; for 48h; Inert atmosphere; Sealed vial;

With trifluoroacetic acid; at 20 ℃; for 0.333333h;
DOI:10.1002/anie.201106150

Reference yield:

: 108-44-1
1-amino-3-methylbenzene

: 76472-83-8
6-methyl-[1,1'-biphenyl]-2-amine

: 54147-94-3
2-amino-4-methylbiphenyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 20 °C

2.1: cesium fluoride / toluene; acetonitrile / 48 h / 110 °C / Inert atmosphere; Sealed vial

2.2: 0.33 h / 20 °C

With triethylamine; cesium fluoride; In dichloromethane; toluene; acetonitrile;
DOI:10.1002/anie.201106150