Benzene, [(methylthio)ethynyl]-

Base Information

Chemical Name:Benzene, [(methylthio)ethynyl]-
CAS No.:7714-33-2
Molecular Formula:C9H8S
Molecular Weight:148.229
Hs Code.:

Synonyms:[(methylthio)ethynyl]benzene;2-Methylsulfanyl-1-phenylethyne;methyl phenylethynyl sulfide;phenylethynyl methyl sulfide;1-(methylthio)-2-phenylethyne;1-methylthio-2-phenylethyne;

Suppliers and Price of Benzene, [(methylthio)ethynyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, [(methylthio)ethynyl]-

Chemical Property:

PSA：25.30000
LogP:2.35860

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzene, [(methylthio)ethynyl]-

There total 26 articles about Benzene, [(methylthio)ethynyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 624-92-0
Dimethyldisulphide

: 536-74-3
phenylacetylene

: 7714-33-2
methyl phenylethynyl sulfide

Guidance literature:: phenylacetylene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

Dimethyldisulphide; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 1h;
DOI:10.1021/acs.orglett.8b03590

Reference yield: 86.8%

: 4973-66-4
methyl thiotosylate

: 536-74-3
phenylacetylene

: 7714-33-2
methyl phenylethynyl sulfide

Guidance literature:: With copper(l) iodide; potassium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In dimethyl sulfoxide; at 20 ℃; for 24h; Solvent; Inert atmosphere;
DOI:10.1021/acs.orglett.9b00875

Reference yield: 86.0%

: 536-74-3
phenylacetylene

: 74-88-4
methyl iodide

: 7714-33-2
methyl phenylethynyl sulfide

Guidance literature:: phenylacetylene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

With sulfur; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;

methyl iodide; Further stages;
DOI:10.1002/hc.20744