(1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

Base Information

Chemical Name:(1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
CAS No.:80513-77-5
Molecular Formula:C10H16O2
Molecular Weight:168.236
Hs Code.:
DSSTox Substance ID:DTXSID80504399
Nikkaji Number:J676.190I
Wikidata:Q82358873

Synonyms:(1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one;80513-77-5;DTXSID80504399

Suppliers and Price of (1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:168.115029749
Heavy Atom Count:12
Complexity:244

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC1(C(=O)C2O)C)C
Isomeric SMILES:C[C@]12CC[C@H](C1(C)C)[C@@H](C2=O)O

Technology Process of (1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

There total 20 articles about (1S,3S,4R)-3-Hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 15795-31-0,31658-22-7,31658-57-8,83462-15-1,91839-98-4,125409-78-1
Acetic acid (1S,4R)-4,7,7-trimethyl-3-oxo-bicyclo[2.2.1]hept-2-yl ester

: 10373-81-6,21488-68-6,22759-33-7,24326-34-9,28357-09-7,28357-11-1,80513-77-5,80513-78-6,82264-38-8
3-hydroxycamphor

Guidance literature:: With potassium hydroxide; In methanol;
DOI:10.1016/S0040-4020(01)89491-6

Reference yield: 31.0%

: (+)-2-exo-3-exo-camphane-2,3-diol

: 2767-84-2
(1S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione

: 19427-85-1
(+)-2β-hydroxybornan-3-one

: 80513-77-5
1,7,7-trimethyl-3-hydroxybicyclo[2.2.1]-heptan-2-one

: 595-31-3
(+)-(1S,3R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic anhydride

Guidance literature:: With pyridine; chlorine dioxyde; at 20 ℃; for 1h; Reagent/catalyst; Time;
DOI:10.1134/S1070363214050120

Reference yield:

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 107438-74-4,1126-88-1,1607-84-7,4367-83-3,13948-58-8,22285-79-6
5-endo-hydroxy-1,7,7-trimethylbicyclo<2.2.1>heptan-2-one

: 28357-11-1
(+)-3R-exo-hydroxycamphor

: 10373-81-6,21488-68-6,22759-33-7,24326-34-9,28357-11-1,80513-77-5,80513-78-6,82264-38-8,28357-09-7
(-)-(3S)-endo-hydroxycamphor

Guidance literature:: With cindoxin; Escherichia coli flavodoxin reductase; N₂₄₂T mutant; NADPH; catalase; In aq. buffer; at 25 ℃; for 0.5h; Enzymatic reaction;
DOI:10.1016/j.abb.2019.07.025