Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(trifluoromethyl)-

Base Information

• Chemical Name: Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(trifluoromethyl)-
• CAS No.: 815-28-1
• Molecular Formula: C4F11N
• Molecular Weight: 271.033
• Mol file: 815-28-1.mol

Synonyms:

Chemical Property of Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(trifluoromethyl)-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(trifluoromethyl)-

There total 10 articles about Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.9%

methyl 3-dimethylamino-n-butyrate (33598-36-6) → perfluoro(dimethylethylamine) (815-28-1) + perfluoro(N,N-dimethyl-n-propylamine) (103217-78-3) + heptafluoropropyl trifluoromethyl ether (59426-77-6) + perfluoro(3-dimethylamino-n-butyryl fluoride) (123320-67-2)

Guidance literature:

With hydrogen fluoride; at 7 - 8 ℃; for 8.48333h; Further byproducts given; electrochemical reaction; anodic current density of 3.5 A dm^-2, a cell voltage of 6.1 V - 6.2 V;

DOI:10.1016/0022-1139(93)03019-I

Reference yield: 11.0%

methyl 3-(dimethylamino)propionate (3853-06-3) → perfluoropropanoyl fluoride (422-61-7) + perfluoro(dimethylethylamine) (815-28-1) + N-trifluoromethyl-N-difluoromethylpentafluoro(3,4-dimethyloxazolidine) (77314-41-1) + Perfluoro<3-(N,N-dimethylamino)propionyl> fluoride (124008-11-3)

Guidance literature:

With hydrogen fluoride; at 7 - 8 ℃; for 9.11667h; Further byproducts given; electrolysis (3.5 A/dm², 6.0 to 6.1 V);

DOI:10.1016/S0022-1139(00)80438-8

Reference yield: 6.0%

methyl 3-(dimethylamino)propionate (3853-06-3) → perfluoropropanoyl fluoride (422-61-7) + perfluorotrimethylamine (432-03-1) + perfluoro(dimethylethylamine) (815-28-1) + Perfluoro<3-(N,N-dimethylamino)propionyl> fluoride (124008-11-3)

Guidance literature:

With hydrogen fluoride; at 7 - 8 ℃; for 9.11667h; Further byproducts given; electrolysis (3.5 A/dm², 6.0 to 6.1 V);

DOI:10.1016/S0022-1139(00)80438-8

upstream raw materials:

methyl 3-(dimethylamino)propionate

methyl 2-diethylamino-propionate

methyl 3-dimethylamino-n-butyrate

N,N,N,N,-tetramethylethylenediamine

Downstream raw materials:

carbon tetrafluoride

trifluoroacetonitrile

2,4,6-tris(trifluoromethyl)-1,3,5-triazine

Refernces

• 1、 Abe, Takashi,Baba, Hajime,Soloshonok, Irina. "Electrochemical fluorination of 1-ethylpiperazine and 4-methyl- and/or 4-ethylpiperazinyl substituted carboxylic acid methyl esters". . p. 21 - 35. Retrieved 2007/10/03.
• 2、 Dimitrov,Pfeifer,Jonethal,Ruediger,Seppelt. "Mechanistic studies on the electrochemical fluorination of trialkylamines and tetraalkylammonium salts". . p. 143 - 150. Retrieved 2007/10/03.