Silane, [[2-[dibromo(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

Base Information

• Chemical Name: Silane, [[2-[dibromo(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-
• CAS No.: 820217-14-9
• Molecular Formula: C51H94Br2Si6Sn
• Molecular Weight: 1154.31000
• Mol file: 820217-14-9.mol

Synonyms:

Chemical Property of Silane, [[2-[dibromo(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

Chemical Property:

• PSA: 0.00000
• LogP: 17.97760

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, [[2-[dibromo(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl-

There total 4 articles about Silane, [[2-[dibromo(2,4,6-tricyclohexylphenyl)stannyl]-1,3,5-benzenetriyl]trimeth ylidyne]hexakis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-25-2) + bromine (7726-95-6) → dibromo(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-14-9)

Guidance literature:

In diethyl ether; (Ar); Br2 added to a soln. of Sn compd.; solvent-removed, recrystd. (EtOH); elem. anal.;

DOI:10.1021/ja048453h

Reference yield:

(2-bromobenzene-1,3,5-triyl)tricyclohexane (97443-80-6) → dibromo(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-14-9)

Guidance literature:

Multi-step reaction with 3 steps

1: t-BuLi; Mg; I₂ / pentane; tetrahydrofuran

2: LiAlH₄ / tetrahydrofuran

3: diethyl ether

With t-BuLi; Mg; I₂; LiAlH₄; In tetrahydrofuran; diethyl ether; pentane;

DOI:10.1021/ja048453h

Reference yield:

dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-08-1) → dibromo(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane (820217-14-9)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / tetrahydrofuran

2: diethyl ether

With LiAlH₄; In tetrahydrofuran; diethyl ether;

DOI:10.1021/ja048453h

upstream raw materials:

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

bromine

(2-bromobenzene-1,3,5-triyl)tricyclohexane

dichloro(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-tricyclohexylphenyl)stannane

Downstream raw materials:

5-(2,4,6-tricyclohexylphenyl)-5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,2,3,4,5-tetraselenastannolane

2,4,6-tris[bis(trimethylsilyl)methyl]phenyl(2,4,6-tricyclohexylphenyl)Sn=Se

2,4,6-tris[bis(trimethylsilyl)methyl]phenyl(2,4,6-tricyclohexylphenyl)Sn=S

2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-tricyclohexylphenyl)-4-phenylimino-1,3,2-dithiastannetane

Refernces