Cyclohexyldisulfanyldisulfanyl-cyclohexane

Base Information

• Chemical Name: Cyclohexyldisulfanyldisulfanyl-cyclohexane
• CAS No.: 83859-40-9
• Molecular Formula: C12H22S4
• Molecular Weight: 294.571
• DSSTox Substance ID: DTXSID00510558
• Nikkaji Number: J2.190.041I
• Wikidata: Q82368900
• Mol file: 83859-40-9.mol

Synonyms:83859-40-9;cyclohexyldisulfanyldisulfanyl-cyclohexane;Dicyclohexyltetrasulfane;1,4-dicyclohexyltetrasulfane;DTXSID00510558;AKOS015906395

Chemical Property of Cyclohexyldisulfanyldisulfanyl-cyclohexane

Chemical Property:

• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 294.06043540
• Heavy Atom Count: 16
• Complexity: 154

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)SSSSC2CCCCC2

Technology Process of Cyclohexyldisulfanyldisulfanyl-cyclohexane

There total 12 articles about Cyclohexyldisulfanyldisulfanyl-cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

methoxycarbonylhydrazone of cyclohexanone (14702-42-2) → dicyclohexyl tetrasulfide (83859-40-9)

Guidance literature:

With hydrogen sulfide; acetic acid; In methanol; at 90 ℃; for 72h;

DOI:10.1055/s-1982-29962

Reference yield: 82.0%

Cyclohexanethiol (1569-69-3) → dicyclohexyl tetrasulfide (83859-40-9)

Guidance literature:

With disulfur dichloride; triethylamine; In diethyl ether; at -78 - 20 ℃; for 1.5h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.1c02636

Reference yield:

Cyclohexanecarboxylic acid 2-thioxo-2H-pyridin-1-yl ester (105398-69-4) → 2,2'-dipyridyldisulphide (2127-03-9) + dicyclohexyl tetrasulfide (83859-40-9) + 2-(cyclohexylsulfanyl)pyridine (119520-56-8) + C11H15NS3

Guidance literature:

With sulfur; In dichloromethane; at 0 ℃; for 1h; Yield given. Yields of byproduct given; Irradiation;

DOI:10.1016/0040-4039(94)88074-3

upstream raw materials:

Cyclohexanethiol

methoxycarbonylhydrazone of cyclohexanone

Cyclohexanecarboxylic acid 2-thioxo-2H-pyridin-1-yl ester

C₁₂H₂₂S₃

Downstream raw materials:

dicyclohexyl sulfide

dicyclohexyl sulfone