3-Cyclohexylidenecarbazic acid methyl ester

Base Information

• Chemical Name: 3-Cyclohexylidenecarbazic acid methyl ester
• CAS No.: 14702-42-2
• Molecular Formula: C8H14N2O2
• Molecular Weight: 170.211
• Mol file: 14702-42-2.mol

Synonyms:carbomethoxyhydrazone of cyclohexanone;Cyclohexanone carbomethoxyhydrazone;2-Cyclohexyliden-hydrazincarbonsaeure-methylester;

Chemical Property of 3-Cyclohexylidenecarbazic acid methyl ester

Chemical Property:

• PKA: 10.70±0.20(Predicted)
• PSA: 50.69000
• Density: 1.17±0.1 g/cm3(Predicted)
• LogP: 2.05340

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Cyclohexylidenecarbazic acid methyl ester

There total 1 articles about 3-Cyclohexylidenecarbazic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

hydrazinecarboxylic acid methyl ester (6294-89-9) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → methoxycarbonylhydrazone of cyclohexanone (14702-42-2)

Guidance literature:

With acetic acid; In methanol; for 0.5h; Heating;

DOI:10.1055/s-1982-29962

Reference yield: 92.0%

hydrogen cyanide (74-90-8) + methoxycarbonylhydrazone of cyclohexanone (14702-42-2) → 1-(1-Cyanocyclohexyl)-2-carbomethoxyhydrazine (61827-29-0)

Guidance literature:

Aliquat 336; In hexane; water; for 2h;

DOI:10.1055/s-1990-26831

Reference yield: 89.0%

methoxycarbonylhydrazone of cyclohexanone (14702-42-2) → dicyclohexyl tetrasulfide (83859-40-9)

Guidance literature:

With hydrogen sulfide; acetic acid; In methanol; at 90 ℃; for 72h;

DOI:10.1055/s-1982-29962

upstream raw materials:

hydrazinecarboxylic acid methyl ester

cyclohexanone

Downstream raw materials:

N-(methoxycarbonylamino)cyclohexylamine

1-(1-Cyanocyclohexyl)-2-carbomethoxyhydrazine

cyclohexane carbonitrile

carbonic acid dimethyl ester

Refernces

• 1、 Pezacki, John Paul,Couture, Philippe,Dunn, James A.,Warkentin, John,Wood, Paul D.,Lusztyk, Janusz,Ford, Francis,Platz, Matthew S.. "Rate constants for 1,2-hydrogen migration in cyclohexylidene and in substituted cyclohexylidenes". . p. 4456 - 4464. Retrieved 2007/10/03.
• 2、 Ballini, Roberto. "Reaction of Methoxycarbonylhydrazones with Hydrogen Sulfide: A New and Facile Synthesis of Tetrasulfides". . p. 834 - 836. Retrieved 2007/10/02.