2-Methyl-1-(2-methylprop-1-enoxy)prop-1-ene

Base Information

• Chemical Name: 2-Methyl-1-(2-methylprop-1-enoxy)prop-1-ene
• CAS No.: 764-51-2
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• NSC Number: 43340
• DSSTox Substance ID: DTXSID10285967
• Nikkaji Number: J843.968K

Synonyms:764-51-2;2-methyl-1-(2-methylprop-1-enoxy)prop-1-ene;isobutenyl ether;NSC43340;SCHEMBL2811099;DTXSID10285967;NSC-43340;2-Methyl-1-(2-methyl-propenyloxy)-propene

Chemical Property of 2-Methyl-1-(2-methylprop-1-enoxy)prop-1-ene

Chemical Property:

• Vapor Pressure: 5.73mmHg at 25°C
• Boiling Point: 146.9°Cat760mmHg
• Flash Point: 33°C
• Density: 0.82g/cm³
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 126.104465066
• Heavy Atom Count: 9
• Complexity: 108

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=COC=C(C)C)C

Technology Process of 2-Methyl-1-(2-methylprop-1-enoxy)prop-1-ene

There total 7 articles about 2-Methyl-1-(2-methylprop-1-enoxy)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

2-Methyl-1-[2-methyl-1-(2-methyl-propenyloxy)-propoxy]-propene → Bis(2-methylprop-1-enyl) ether (764-51-2) + isobutyraldehyde (78-84-2)

Guidance literature:

With toluene-4-sulfonic acid; Heating;

DOI:10.1002/(sici)1097-458x(199702)35:2<107::aid-omr26>3.0.co;2-y

Reference yield: 26.0%

2,2,4,4-tetramethyl-6-oxabicyclo<3.1.0>hexan-3-one (97455-13-5) → dimethylketene (598-26-5) + 2,5-Dimethyl-2,4-hexadiene (764-13-6) + 3,3-dimethyl acrylaldehyde (107-86-8) + Bis(2-methylprop-1-enyl) ether (764-51-2)

Guidance literature:

In pentane; Further byproducts given; Irradiation;

DOI:10.1016/S0040-4039(00)89162-5

Reference yield: 26.0%

2,2,4,4-tetramethyl-6-oxabicyclo<3.1.0>hexan-3-one (97455-13-5) → dimethylketene (598-26-5) + 2,2-dimethyl-3-(2-methylprop-1-enyl)oxirane (13295-59-5) + 2,5-dimethyl-hex-4-en-3-one (13905-13-0) + 2,5-Dimethyl-2,4-hexadiene (764-13-6) + 3,3-dimethyl acrylaldehyde (107-86-8) + Bis(2-methylprop-1-enyl) ether (764-51-2)

Guidance literature:

In pentane; Mechanism; Irradiation;

DOI:10.1016/S0040-4039(00)89162-5

upstream raw materials:

2,2,4,4-tetramethyl-6-oxabicyclo<3.1.0>hexan-3-one

Downstream raw materials:

Bis-(2-chlor-2-phenyl-3,3-dimethyl-cyclopropyl)-ether

2,2,4-trimethyl-pent-3-enal

tetramethyl-succinaldehyde

isobutyraldehyde

Refernces

Novel synthesis of macrocycles with chalcone moieties through mixed aldol reaction

10.1016/S0040-4039(01)01793-2

The research focuses on the novel synthesis of 24-membered macrocycles with chalcone structural moieties and isobutenyl ether linkages in the core, which are significant for molecular recognition and photophysical properties. The purpose of this study is to incorporate chalcone moieties into macrocyclic structures, leveraging their well-exploited photophysical properties for various optical applications. The researchers envisioned that these macrocycles could be useful for molecular recognition studies and as photo-functional materials. The synthesis strategy involved a mixed aldol reaction of bis-arylaldehyde and bis-arylmethyl ketone, expected to yield a macrocycle with two chalcone moieties and two isobutenyl ether linkages. The study successfully demonstrated a novel approach to synthesize these macrocycles, which possess potential for further modifications under thermal conditions, as shown in the conversion of macrocycle 8a to 9a. The chemicals used in the process include t-BuOK as a catalyst, THF as a solvent, and various substituted aryl groups on the aldehyde and ketone compounds, such as chloro, methoxy, and methyl groups. The synthesized macrocycles were fully characterized using IR, NMR, and ESI-MS techniques. The conclusions drawn from the research indicate that the presence of two isobutenyl ether linkages in the macrocycles are useful for modifications of the macrocycle core under thermal conditions, and the photophysical and molecular recognition properties of these macrocycles will be the focus of future studies.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 764-51-2 2-methyl-1-[(2-methylprop-1-en-1-yl)oxy]prop-1-ene

Send

Send

Metric Ton KG G Pound L ML

Send

Send