Pentachlorofluoroethane

Base Information

• Chemical Name: Pentachlorofluoroethane
• CAS No.: 354-56-3
• Deprecated CAS: 29756-45-4
• Molecular Formula: C2Cl5F
• Molecular Weight: 220.285
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID6059869
• Nikkaji Number: J5.210H
• Wikipedia: Pentachlorofluoroethane
• Wikidata: Q7164937
• Mol file: 354-56-3.mol

Synonyms:Fluoropentachloroethane;354-56-3;PENTACHLOROFLUOROETHANE;1,1,1,2,2-pentachloro-2-fluoroethane;CFC-111;Ethane, pentachlorofluoro-;Ethane, 1,1,1,2,2-pentachloro-2-fluoro-;C2Cl5F;Pentachloro fluoro ethane;C2-Cl5-F;SCHEMBL1221821;DTXSID6059869;MFCD00069093;AKOS025310369;FT-0626481;A822823;1,1,1,2,2-pentakis(chloranyl)-2-fluoranyl-ethane;Q7164937

Chemical Property of Pentachlorofluoroethane

Chemical Property:

• Vapor Pressure: 9.04mmHg at 25°C
• Melting Point: 100-101 °C
• Refractive Index: 1.486
• Boiling Point: 136.7 °C at 760 mmHg
• Flash Point: 40.8 °C
• PSA: 0.00000
• Density: 1.776 g/cm³
• LogP: 3.45750
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 219.839717
• Heavy Atom Count: 8
• Complexity: 82.9

Purity/Quality:

98%Min ^*data from raw suppliers

Pentachlorofluoroethane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(Cl)(Cl)Cl)(F)(Cl)Cl

Technology Process of Pentachlorofluoroethane

There total 22 articles about Pentachlorofluoroethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

1,1,2,2-tetrachloroethylene (127-18-4) + ethanol (64-17-5) + ethyl acetate (141-78-6) → freon-111 (354-56-3) + Ethyl trichloroacetate (515-84-4)

Guidance literature:

With chlorine monofluoride; Yield given. Multistep reaction; 1.) Freon 113; 2.) 20 - 25 deg C, 30 min.;

Reference yield:

1,1,1-Trichloro-2,2,2-trifluoroethane (354-58-5) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1-difluorotetrachloroethane (76-11-9) + 1,1-dichlorotetrafluoroethane (374-07-2) + freon-111 (354-56-3)

Guidance literature:

With aluminum oxide; Dichlorodifluoromethane; at 319.85 ℃; Further Variations:; Temperatures; Product distribution;

DOI:10.1016/S0022-1139(00)00350-X

Reference yield:

1,1-difluorotetrachloroethane (76-11-9) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,1-Trichloro-2,2,2-trifluoroethane (354-58-5) + 1,1-dichlorotetrafluoroethane (374-07-2) + freon-111 (354-56-3)

Guidance literature:

With aluminum oxide; Dichlorodifluoromethane; at 439.85 ℃; Further Variations:; Temperatures; Product distribution;

DOI:10.1016/S0022-1139(00)00350-X

upstream raw materials:

1,1,2,2-tetrachloroethylene

1,1,2-trichloro-2-fluoroethane

hexachloroethane

chlorofluoroacetylene

Downstream raw materials:

trichlorofluoroethene

Refernces

• 1、 Bozorgzadeh, Hamid,Kemnitz, Erhard,Nickkho-Amiry, Mahmood,Skapin, Toma?,Winfield, John M.. "Dynamic behaviour of chlorofluoroethanes at fluorinated chromia aerogels and fluorinated zinc(II) or magnesium(II) doped chromia aerogels". . p. 83 - 92. Retrieved 2007/10/03.
• 2、 Batiot, Catherine,Brunet, Sylvette,Barrault, Joel,Blanchard, Michel. "Catalytic Liquid-phase Fluorination of Tetrachlorethene (PCE) with Titanium Antimony Mixed Halides". . p. 867 - 868. Retrieved 2007/10/02.