Phosphorous acid,tris(2-chlorophenyl) ester

Base Information

• Chemical Name: Phosphorous acid,tris(2-chlorophenyl) ester
• CAS No.: 24460-31-9
• Molecular Formula: C18H12 Cl3 O3 P
• Molecular Weight: 413.624
• Mol file: 24460-31-9.mol

Synonyms:Phosphorousacid, tris(o-chlorophenyl) ester (8CI); Tris(2-chlorophenyl) phosphite;Tris(o-chlorophenyl) phosphite

Chemical Property of Phosphorous acid,tris(2-chlorophenyl) ester

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphorous acid,tris(2-chlorophenyl) ester

There total 1 articles about Phosphorous acid,tris(2-chlorophenyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-monochlorophenol (95-57-8) → tri-(2-chlorophenyl) phosphite (24460-31-9)

Guidance literature:

With phosphorus trichloride;

DOI:10.1021/ja01521a028

Reference yield: 90.0%

tri-(2-chlorophenyl) phosphite (24460-31-9) + N2-(Benzyloxycarbonyl)-N1-(1'-methoxy-2'-methylpropyl)-L-alaninamid (104173-19-5,104173-20-8) → Bis(2-chlorophenyl)-N-(benzyloxycarbonyl)-L-alanyl-(2-decarboxy-DL-valin-2-yl)phosphonat

Guidance literature:

With titanium tetrachloride; In dichloromethane; for 10h; -78 deg c -> room temperature;

DOI:10.1002/hlca.19890720302

Reference yield: 33.0%

tri-(2-chlorophenyl) phosphite (24460-31-9) + O4-Benzyl-N2-(benzyloxycarbonyl)-N1,N1-(2-methoxytetramethylene)-L-tyrosinamid → Bis(2-chlorophenyl)-O-benzyl-N-(benzyloxycarbonyl)-L-tyrosyl-(2-decarboxy-DL-prolin-2-yl)phosphonat

Guidance literature:

In dichloromethane; for 10h; -78 deg C -> room temperature;

DOI:10.1002/hlca.19890720302

upstream raw materials:

2-monochlorophenol

Downstream raw materials:

phosphonic acid bis-(2-chloro-phenyl ester)

tri-(2-chlorophenyl) phosphite ozonide

bis(2-chlorophenyl) chlorophosphate

O,O-di-2-chlorophenyl methylphosphonate