Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate

Base Information

Chemical Name:Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate
CAS No.:22027-52-7
Molecular Formula:C13H14O5
Molecular Weight:250.2473
Hs Code.:29189990
European Community (EC) Number:674-335-1
DSSTox Substance ID:DTXSID90397557
Nikkaji Number:J3.136.762J
Wikidata:Q82199013
Mol file:22027-52-7.mol

Synonyms:methyl 4-(3-methoxy-3-oxopropanoyl)benzoate;22027-52-7;Methyl 4-methoxycarbonylbenzoylacetate;METHYL4-METHOXYCARBONYLBENZOYLACETATE;MFCD00800637;4-(2-Methoxycarbonyl-acetyl)-benzoic acid methyl ester;SCHEMBL333688;DTXSID90397557;PAGMDUGVIOXELP-UHFFFAOYSA-N;AKOS015852178;AS-18935;SY030637;CS-0199035;FT-0676529;FT-0732421;H11397;4-methoxycarbonylbenzoyl acetic acid methyl ester;EN300-1826862;A878798;methyl 4-methoxycarbonylbenzoylacetate, AldrichCPR;4-[2-(Methoxycarbonyl)-1-oxoethyl]benzoic acid methyl ester

Suppliers and Price of Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl4-Methoxycarbonylbenzoylacetate
500mg
$ 90.00

SynQuest Laboratories
Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate
25 g
$ 549.00

SynQuest Laboratories
Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate
1 g
$ 76.00

SynQuest Laboratories
Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate
5 g
$ 149.00

Matrix Scientific
Methyl 4-methoxycarbonylbenzoylacetate
5g
$ 130.00

Matrix Scientific
Methyl 4-methoxycarbonylbenzoylacetate
1g
$ 32.00

Crysdot
Methyl4-(3-methoxy-3-oxopropanoyl)benzoate 97%
5g
$ 386.00

Crysdot
Methyl4-(3-methoxy-3-oxopropanoyl)benzoate 97%
1g
$ 114.00

Apolloscientific
Methyl4-(3-methoxy-3-oxopropanoyl)benzoate 95+%
1g
$ 143.00

Apolloscientific
Methyl4-(3-methoxy-3-oxopropanoyl)benzoate 95+%
5g
$ 238.00

Total 15 raw suppliers

Chemical Property of Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate

Chemical Property:

Vapor Pressure:1.76E-05mmHg at 25°C
Melting Point:57-62 °C
Refractive Index:1.5140 (estimate)
Boiling Point:363.8 °C at 760 mmHg
Flash Point:160.4 °C
PSA：43.37000
Density:1.181 g/cm³
LogP:2.45120
Storage Temp.:2-8°C
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:6
Exact Mass:236.06847348
Heavy Atom Count:17
Complexity:302

Purity/Quality:

97% ^*data from raw suppliers

Methyl4-Methoxycarbonylbenzoylacetate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CC(=O)C1=CC=C(C=C1)C(=O)OC

Technology Process of Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate

There total 2 articles about Methyl 4-(3-methoxy-3-oxopropanoyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 22027-52-7
4-(2-methoxycarbonyl-acetyl)-benzoic acid methyl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; for 17h; Reflux;

Reference yield: 48.0%

: 67-56-1
methanol

: 201230-82-2
carbon monoxide

: 126629-81-0
methyl 3-(4-bromophenyl)-3-oxopropanoate

: 22027-52-7
4-(2-methoxycarbonyl-acetyl)-benzoic acid methyl ester

Guidance literature:: With N-ethyl-N,N-diisopropylamine; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; In N,N-dimethyl-formamide; at 70 ℃; for 4h;