Indium, hydroxydiphenyl-

Base Information

• Chemical Name: Indium, hydroxydiphenyl-
• CAS No.: 873223-22-4
• Molecular Formula: C12H11InO
• Molecular Weight: 286.039
• Mol file: 873223-22-4.mol

Synonyms:

Chemical Property of Indium, hydroxydiphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Indium, hydroxydiphenyl-

There total 1 articles about Indium, hydroxydiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water (7732-18-5) + indium(III) chloride (10025-82-8) + phenylmagnesium bromide (100-58-3) → diphenylindium hydroxide (873223-22-4)

Guidance literature:

In tetrahydrofuran; Ar, stoich., a soln. of Mg compd. added dropwise to a soln. of In compd.at 0°C, stirred for 30 min, water added at 0°C, stirred f or 10 min at room temp.;

DOI:10.1039/b511779h

Reference yield:

diphenylindium hydroxide (873223-22-4) + cyclohexenone (930-68-7) + phenylmagnesium bromide → (R)-3-phenylcyclohexanone (20795-53-3,57344-86-2,113829-97-3,34993-51-6) + (S)-3-phenylcyclohexanone (57344-86-2)

Guidance literature:

phenylmagnesium bromide; With indium(III) chloride; In tetrahydrofuran; at 20 ℃; for 0.5h;

With water; In tetrahydrofuran; at 20 ℃; for 0.166667h;

diphenylindium hydroxide; cyclohexenone; With potassium hydroxide; chiral bicyclo[2.2.2]-octa-2,5-diene; chloro(ethylene)rhodium(I) dimer; In tetrahydrofuran; at 20 ℃; for 24h; Title compound not separated from byproducts;

DOI:10.1039/b511779h

upstream raw materials:

water

indium(III) chloride

phenylmagnesium bromide

Downstream raw materials:

(R)-3-phenylcyclohexanone

(S)-3-phenylcyclohexanone