(Z)-Prop-1-en-1-ylboronic acid

Base Information

• Chemical Name: (Z)-Prop-1-en-1-ylboronic acid
• CAS No.: 6336-44-3
• Molecular Formula: C₃H₇BO₂
• Molecular Weight: 85.8984
• NSC Number: 39118
• Nikkaji Number: J2.283.291C
• Mol file: 6336-44-3.mol

Synonyms:7547-96-8;cis-1-Propene-1-boronic acid;cis-Propenylboronic acid;(Z)-Prop-1-en-1-ylboronic acid;cis-1-Propen-1-ylboronic acid;[(Z)-prop-1-enyl]boronic acid;(Z)-1-propenylboronic acid;6336-44-3;NSC39118;cis-propene boronic acid;cis-propenyl boronic acid;(Z)-propenylboronic acid;cis-1-propenylboronic acid;(Z)-prop-1-enylboronic acid;(Z)-prop-1-enyl boronic acid;CBMCZKMIOZYAHS-IHWYPQMZSA-N;(1Z)-1-propen-1-ylboronic acid;MFCD04039917;NSC-39118;(1Z)-prop-1-en-1-yl boronic acid;AKOS015836299;cis-1-Propen-1-ylboronic acid, >=95.0%;CS-0129385;D78549;A838428

Chemical Property of (Z)-Prop-1-en-1-ylboronic acid

Chemical Property:

• Boiling Point: 175.6°Cat760mmHg
• Flash Point: 60°C
• Density: 0.969g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 86.0539096
• Heavy Atom Count: 6
• Complexity: 50.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: B(C=CC)(O)O
• Isomeric SMILES: B(/C=C\C)(O)O

Technology Process of (Z)-Prop-1-en-1-ylboronic acid

There total 30 articles about (Z)-Prop-1-en-1-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

potassium (E)-trifluoro(prop-1-en-1-yl)trifluoroborate → (E)-propenylboronic acid (6336-44-3,7547-96-8,88982-39-2,7547-97-9)

Guidance literature:

With water; silica gel; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jo901441u

Reference yield: 77.0%

1-propenylmagnesium bromide (13154-14-8,13154-15-9,14092-04-7,1730-25-2) → (E)-propenylboronic acid (6336-44-3,7547-96-8,88982-39-2,7547-97-9)

Guidance literature:

1-propenylmagnesium bromide; With Trimethyl borate; In tetrahydrofuran; at 0 - 20 ℃; for 2.5h;

With hydrogenchloride; In tetrahydrofuran; water; at 0 - 20 ℃; for 0.583333h;

Reference yield: 53.0%

Trimethyl borate (121-43-7,63156-11-6) + 2,2-Dimethyl-1,3-propanediol (126-30-7) + allylmagnesium bromide (1730-25-2) → allylboronic acid (6336-44-3,7547-96-8,7547-97-9,88982-39-2)

Guidance literature:

Trimethyl borate; allylmagnesium bromide; In diethyl ether; at -78 - 0 ℃; for 3h;

With hydrogenchloride; at 0 ℃; for 0.5h;

2,2-Dimethyl-1,3-propanediol; In diethyl ether;

DOI:10.1021/ja509029h

upstream raw materials:

Trimethyl borate

1-propenylmagnesium bromide

(1-propenyl)dichlorobrane

C₈H₁₂BNO₄

Downstream raw materials:

C₈H₁₂BNO₄

(Z)-4,4,5,5-tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane

(Z)-1-acetyl-2-(2-methylethenyl)benzene

(E)-1-acetyl-2-(2-methylethenyl)benzene