oxo-(oxorheniooxy)rhenium; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-6H-pyridin-2-amine; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-3,4,5,6-tetrahydro-2H-pyridin-2-amine; tetrahydrochloride

Base Information

• Chemical Name: oxo-(oxorheniooxy)rhenium; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-6H-pyridin-2-amine; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-3,4,5,6-tetrahydro-2H-pyridin-2-amine; tetrahydrochloride
• CAS No.: 7230-46-8
• Molecular Formula: C₁₅H₁₇NO₂S
• Molecular Weight: 275.371
• Mol file: 7230-46-8.mol

Synonyms:Toluol-4-sulfonsaeure-(2,6-diaethyl-anilid);Toluol-4-sulfonsaeure-(2-aethyl-anilid);Benzenesulfonamide,N-(2,6-diethyl-4-nitrophenyl)-4-methyl;N-(2,6-diethyl-4-nitro phenyl)-4-methyl-benzenesulfonamide;toluene-4-sulfonic acid-(2-ethyl-anilide);toluene-4-sulfonic acid-(2,6-diethyl-anilide);toluene-4-sulfonic acid-(2,6-diethyl-4-nitro-anilide);N-(2,6-Diaethyl-phenyl)-p-toluolsulfonamid;Toluol-4-sulfonsaeure-(2,6-diaethyl-4-nitro-anilid);2-p-Toluolsulfonylamino-1-aethyl-benzol;

Chemical Property of oxo-(oxorheniooxy)rhenium; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-6H-pyridin-2-amine; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-3,4,5,6-tetrahydro-2H-pyridin-2-amine; tetrahydrochloride

Chemical Property:

• Boiling Point: 285.6°Cat760mmHg
• Flash Point: 129.5°C
• PSA: 24.06000
• Density: g/cm³
• LogP: 5.54340

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxo-(oxorheniooxy)rhenium; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-6H-pyridin-2-amine; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-3,4,5,6-tetrahydro-2H-pyridin-2-amine; tetrahydrochloride

There total 2 articles about oxo-(oxorheniooxy)rhenium; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-6H-pyridin-2-amine; N-(3,4,5,6-tetrahydro-2H-pyridin-2-yl)-3,4,5,6-tetrahydro-2H-pyridin-2-amine; tetrahydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylbenzene (100-41-4,27536-89-6) + [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5) → toluene-4-sulfonic acid-(2-ethyl-anilide) (7230-46-8) + toluene-4-sulfonic acid-(4-ethyl-anilide) (1506-96-3) + N-(1-phenylethyl)-p-toluenesulfonamide (4809-56-7)

Guidance literature:

With [(tris(3,5-dimethylpyrazol-1-yl)methane)Fe(NCMe)₃](BF₄)₂; In dichloromethane; at 19.84 ℃; Overall yield = 62 %; regioselective reaction;

DOI:10.1021/om3009102

Reference yield:

→ toluene-4-sulfonic acid-(2-ethyl-anilide) (7230-46-8)

Guidance literature:

2-Aethyl-anilin, p-Toluolsulfonsaeure-chlorid; Ausbeute 72percent;

Reference yield:

toluene-4-sulfonic acid-(2-ethyl-anilide) (7230-46-8) → [(2-ethyl-phenyl)-(toluene-4-sulfonyl)-amino]-acetic acid (335416-47-2)

Guidance literature:

Multi-step reaction with 2 steps

1: NaH / dimethylformamide

2: aq. NaOH / ethanol

With sodium hydroxide; sodium hydride; In ethanol; N,N-dimethyl-formamide;

DOI:10.1016/j.bmcl.2007.06.014

upstream raw materials:

ethylbenzene

[N-(p-tolylsulfonyl)imino]phenyliodinane

Downstream raw materials:

[(2-ethyl-phenyl)-(toluene-4-sulfonyl)-amino]-acetic acid

C₂₅H₂₇N₃SO₆