2-Bromo-4-methylphenyl 2,2-dimethylpropanoate

Base Information

Chemical Name:2-Bromo-4-methylphenyl 2,2-dimethylpropanoate
CAS No.:87995-48-0
Molecular Formula:C12H15BrO2
Molecular Weight:271.154
Hs Code.:
DSSTox Substance ID:DTXSID90522928
Wikidata:Q82388630

Synonyms:2-Bromo-4-methylphenyl 2,2-dimethylpropanoate;87995-48-0;SCHEMBL9309156;2-bromo-4-methylphenyl pivalate;DTXSID90522928;AKOS002942026

Suppliers and Price of 2-Bromo-4-methylphenyl 2,2-dimethylpropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Bromo-4-methylphenyl 2,2-dimethylpropanoate

Chemical Property:

XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:270.02554
Heavy Atom Count:15
Complexity:232

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C=C1)OC(=O)C(C)(C)C)Br

Technology Process of 2-Bromo-4-methylphenyl 2,2-dimethylpropanoate

There total 1 articles about 2-Bromo-4-methylphenyl 2,2-dimethylpropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 6627-55-0
2-bromo-p-cresol

: 3282-30-2
pivaloyl chloride

: 87995-48-0
(2-Brom-4-methylphenyl)-pivaloat

Guidance literature:

Reference yield: 62.0%

: 87995-48-0
(2-Brom-4-methylphenyl)-pivaloat

: 72569-13-2
2,2-dimethyl-1-(2-hydroxy-5-methylphenyl)-1-propanone

Guidance literature:: With sec.-butyllithium; In tetrahydrofuran; diethyl ether; hexane; at -95 - -78 ℃; for 1h;
DOI:10.1021/jo00378a044

Reference yield:

: 87995-48-0
(2-Brom-4-methylphenyl)-pivaloat

: 614-34-6
p-cresyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) BuLi, 2) aq. NH₄Cl / 1) THF, hexane, -100 deg C, 2) THF, hexane, r.t.

2: 62 percent

With n-butyllithium; ammonium chloride;