Benzeneacetic acid, a-propyl-, ethyl ester

Base Information

Chemical Name:Benzeneacetic acid, a-propyl-, ethyl ester
CAS No.:88223-42-1
Molecular Formula:C13H18O2
Molecular Weight:206.285
Hs Code.:

Synonyms:

Suppliers and Price of Benzeneacetic acid, a-propyl-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Benzeneacetic acid, a-propyl-, ethyl ester

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzeneacetic acid, a-propyl-, ethyl ester

There total 5 articles about Benzeneacetic acid, a-propyl-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 107-08-4
1-iodo-propane

: 101-97-3
Ethyl 2-phenylethanoate

: 88223-42-1
ethyl 2-phenylpentanoate

Guidance literature:: With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/jacs.7b05468

Reference yield: 87.0%

: 106-94-5
propyl bromide

: 101-97-3
Ethyl 2-phenylethanoate

: 88223-42-1
ethyl 2-phenylpentanoate

Guidance literature:: Ethyl 2-phenylethanoate; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

propyl bromide; In tetrahydrofuran; hexane; at 20 ℃; for 16h; Further stages.;
DOI:10.1039/b607211a

Reference yield:

: 2882-19-1,2216-90-2
ethyl 2-phenyl-2-bromoacetate

: 88223-42-1
ethyl 2-phenylpentanoate

Guidance literature:: Multi-step reaction with 2 steps

1: nicotinamide adenine dinucleotide phosphate; D-glucose; glucose dehydrogenase GDH-105; gluconobacter oxydans enoate reductase (GluER), mutant Y₁₇₇F / isopropyl alcohol / 24 h / 25 °C / pH 8 / Inert atmosphere; Sealed tube; Enzymatic reaction

2: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere

With n-butyllithium; D-glucose; glucose dehydrogenase GDH-105; gluconobacter oxydans enoate reductase (GluER), mutant Y₁₇₇F; nicotinamide adenine dinucleotide phosphate; diisopropylamine; In tetrahydrofuran; hexane; isopropyl alcohol;
DOI:10.1021/jacs.7b05468