Stannane, tributyl(cyclohexylidenemethyl)-

Base Information

Chemical Name:Stannane, tributyl(cyclohexylidenemethyl)-
CAS No.:88924-29-2
Molecular Formula:C₁₉H₃₈Sn
Molecular Weight:385.221
Hs Code.:
DSSTox Substance ID:DTXSID30449024

Synonyms:Stannane, tributyl(cyclohexylidenemethyl)-;88924-29-2;TRIBUTYL(CYCLOHEXYLIDENEMETHYL)STANNANE;DTXSID30449024

Suppliers and Price of Stannane, tributyl(cyclohexylidenemethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Stannane, tributyl(cyclohexylidenemethyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:386.199554
Heavy Atom Count:20
Complexity:237

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C=C1CCCCC1

Technology Process of Stannane, tributyl(cyclohexylidenemethyl)-

There total 1 articles about Stannane, tributyl(cyclohexylidenemethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1121-49-9
bromomethylenecyclohexane

: 1461-22-9
tributyltin chloride

: 7439-95-4
magnesium

: 106-93-4
ethylene dibromide

: 88924-29-2
tributyl(cyclohexylidenemethyl)stannane

Guidance literature:: In tetrahydrofuran; addn. of vinyl bromide and ethylene dibromide to Mg in THF (N2 atmosphere), addn. of further vinyl bromide in THF during 1 h at reflux, decantation, addn. of Sn-compd., refluxing (1 h), cooling room temp.); evapn., partition (Et2O-H2O), washing etheral phase (H2O), drying, evapn., distn.; elem. anal.;

Reference yield: 50.0%

: 146334-72-7
3-[1-Iodo-meth-(Z)-ylidene]-2-methylene-cyclohexanol

: 88924-29-2
tributyl(cyclohexylidenemethyl)stannane

: 74483-11-7
(Z)-1-Cyclohexylidene-2-(3'-hydroxy-2'-methylenecyclohexylidene)ethane

Guidance literature:: With dichloro bis(acetonitrile) palladium(II); In N,N-dimethyl-formamide; for 48h; Ambient temperature;
DOI:10.1016/S0040-4039(00)60832-8

Reference yield:

: 88924-29-2
tributyl(cyclohexylidenemethyl)stannane

: 74483-11-7
(Z)-1-Cyclohexylidene-2-(3'-hydroxy-2'-methylenecyclohexylidene)ethane

Guidance literature:: Multi-step reaction with 2 steps

1: (CH₃CN)2PdCl₂ / dimethylformamide / 48 h / Ambient temperature

2: TBAF / tetrahydrofuran / 2 h / Ambient temperature

With dichloro bis(acetonitrile) palladium(II); tetrabutyl ammonium fluoride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo970605m