22843-73-8

Basic information

• Product Name: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin
• Synonyms: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin;Tetra(p-nitrophenyl)porphyrin
• CAS NO: 22843-73-8
• Molecular Formula: C₄₄H₂₆N₈O₈
• Molecular Weight: 794.72604
• Mol File: 22843-73-8.mol
• Article Data: 70

Chemical Properties

• Melting Point: >27 °C
• Appearance: /
• Density: 1.478g/cm³
• Refractive Index: 1.732
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin(22843-73-8)
• EPA Substance Registry System: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin(22843-73-8)

Safety Data

• Hazardous Substances Data: 22843-73-8(Hazardous Substances Data)

Usage

General Description

5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin is a synthetic chemical compound commonly used in the field of biochemistry and organic chemistry. It is a porphyrin derivative consisting of a central tetrapyrrole ring with four 4-nitrophenyl substituents. 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin is known for its ability to bind to metal ions and can serve as a model for the active sites of metalloproteins, making it a valuable tool in studying enzyme catalysis and metalloenzymes. Additionally, 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin has applications in the development of various sensors and photodynamic therapy agents due to its unique electronic and photophysical properties. Overall, this compound plays a crucial role in advancing research and applications in the fields of biochemistry, organic chemistry, and materials science.

InChI:InChI=1/C44H26N8O8/c53-49(54)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)50(55)56)37-21-23-39(47-37)44(28-7-15-32(16-8-28)52(59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)51(57)58/h1-24,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

Upstream product

• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 555-16-8 4-nitrobenzaldehdye 
• 107798-98-1 5-phenyldipyrromethane 
• 100-52-7 benzaldehyde 
• 143859-77-2 2,2'-[(4-nitrophenyl)methylene]bis(1H-pyrrole) 
• 109-97-7 pyrrole 
• 802294-64-0 propionic acid 
• 552-89-6 2-nitro-benzaldehyde 
• 122-85-0 para-acetamidobenzaldehyde 

Downstream Products

• 138072-33-0 5,10,15,20-tetra(4-nitrophenyl) porphyrinato iron chloride 
• 22112-84-1 tetrakis(4-aminophenyl)porphyrin 
• 142781-56-4 trans-<5,15-bis(4-aminophenyl)-10,20-bis(4-nitrophenyl)>porphyrin 
• 142781-57-5 cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin 
• 142781-55-3 5-(4-aminophenyl)-10,15,20-tris(4-nitrophenyl)porphyrin 
• 142781-58-6 <5-(4-nitrophenyl)-10,15,20-tris(4-aminophenyl)>porphyrin 
• 67595-99-7 5,10,15,20-tetrakis(para-aminophenyl)porphyrin nickel(II) 
• 900149-24-8 5,10,15,20-tetra(4-nitrophenyl) porphyrinato cobalt chloride 
• 139466-78-7 5,10,15,20-tetra(4-nitrophenyl) porphyrinato manganese chloride 

Relevant articles and documents

Gold Recovery from E-Waste by Porous Porphyrin-Phenazine Network Polymers

Gold recovery from electronic waste could prevent excessive mining with toxic extractants and provide a sustainable path for recycling precious metals. Unfortunately, no viable recycling is practiced, except burning electronic circuit boards in underdevel

Highly Porous Metalloporphyrin Covalent Ionic Frameworks with Well-Defined Cooperative Functional Groups as Excellent Catalysts for CO2 Cycloaddition

The development of multifunctional heterogeneous catalysts with high porosity and remarkable catalytic activity still remains a challenge. Herein, four highly porous metalloporphyrin covalent ionic frameworks (CIFs) were synthesized by coupling 5,10,15,20

A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples

Cadmium (Cd) which is an extremely toxic could be found in many products like plastics, fossil fuel combustion, cosmetics, water resources, and wastewaters. It is capable of causing serious environmental and health problems such as lung, prostate, renal c

Interfacially synthesized 2D COF thin film photocatalyst: efficient photocatalyst for solar formic acid production from CO2and fine chemical synthesis

The targeted synthesis of an efficient, visible light active, recyclable, freestanding covalent organic framework thin film photocatalyst for multi-faceted photocatalysis is the essence of the proposed work. A simple, scalable, reagent free synthesis of a thin film at the interface of 5,10,15,20-tetra-(4-aminophenyl)porphyrin, 2-vinylbenzene-1,4-dicarbaldehyde in nitrobenzene and aqueous glyoxal affords centimetre sized continuous 2D thin film with substantial stability, flexibility and efficient visible light activity. Strikingly different from the regular imine based COF, the incorporation of the glyoxal unit as a modulator helps in band gap tuning and induces flexibility within the thin film. An interplay between time and concentration helps in achieving a thin film photocatalyst with efficient photocatalytic activity for 1,4-NADH regeneration and selective formic acid formation from CO2. The optimum band edge position of the thin film photocatalyst also enables solar fine chemical synthesisviareductive dehalogenation under visible light illumination with excellent recyclability. The present work gives insight into visible light active thin film formation en route to metal-free sustainable photocatalysis.

Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction

Developing large-scale electrocatalysts using molecular complexes for the oxygen evolution reaction (OER) is of great importance. Herein, four cobalt porphyrins and corroles are deposited on electrode substrates using a simple and fast electropolymerization method. Our results showed that Co-1-P@CC, formed by electropolymerizing Co tetrakis(p-N-pyrrolylphenyl)porphyrin (Co-1-P) on carbon cloth (CC), is the most active OER catalyst in the examined Co porphyrins and corroles in alkaline aqueous solutions by displaying an onset overpotential of 380 mV. Long-term electrolysis tests confirmed the stability of these electropolymerized films by functioning as OER electrocatalysts.