Dichloroplatinum;4-methylpyridine

Base Information

• Chemical Name: Dichloroplatinum;4-methylpyridine
• CAS No.: 72151-35-0
• Molecular Formula: C₁₂H₁₄Cl₂N₂Pt
• Molecular Weight: 452.243
• Mol file: 72151-35-0.mol

Synonyms:

Chemical Property of Dichloroplatinum;4-methylpyridine

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 451.018198
• Heavy Atom Count: 17
• Complexity: 133

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC=NC=C1.CC1=CC=NC=C1.Cl[Pt]Cl

Technology Process of Dichloroplatinum;4-methylpyridine

There total 19 articles about Dichloroplatinum;4-methylpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

picoline (108-89-4) + potassium tetrachloroplatinate(II) (10025-99-7) → trans-[platinum(II) dichloride bis(4-picoline)] (72151-35-0,24476-75-3,52646-74-9)

Guidance literature:

In water; excess of ligand, stirring and heating for 1 h; according to G. B. Kaufmann, Inorg. Synth. 7 (1963) 249;

DOI:10.1016/S0020-1693(99)00303-5

Reference yield: 66.0%

picoline (108-89-4) + trans-dichloro-bis(methyl cyanide)-platinum(II) (13869-42-6,13869-38-0,21264-32-4) → trans-[platinum(II) dichloride bis(4-picoline)] (72151-35-0,24476-75-3,52646-74-9)

Guidance literature:

In benzene; (N2); stirring (room temp., 10 h), pptn.; filtration, washing (benzene), drying (vac.); elem. anal.;

Reference yield: 52.0%

picoline (108-89-4) + K2[PtCl4] → Pt(4-picoline)2Cl2 (72151-35-0,24476-75-3,52646-74-9)

Guidance literature:

In ethanol; water; at 60 ℃; for 0.333333h; Microwave irradiation;

DOI:10.1016/j.ica.2015.07.042

upstream raw materials:

picoline

cis-[meso-1,2-bis(phenylsulphinyl)ethane]dichloroplatinum(II)

cis-[rac-1,2-bis(phenylsulphinyl)ethane]dichloroplatinum(II)

potassium tetrachloroplatinate(II)

Downstream raw materials:

trans-[PtCl (MeBzSO)(pic)2]NO₃

trans-[platinum(II) dichloride bis(4-picoline)]

dichlorido(5,5'-dimethyl-2,2'-bipyridine)platinum(II)

trans-[PtCl(CH₃SOCH₂C₆H₅)(CH₃C₅H₄N)2]NO₃