4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-

Base Information

Chemical Name:4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-
CAS No.:905732-35-6
Molecular Formula:C₃₄H₆₂O₄Si₂
Molecular Weight:591.035
Hs Code.:

4,9-Dioxa-3,10-disiladodecan-6-one,
8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11
-trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-

Synonyms:

Suppliers and Price of 4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)-

There total 9 articles about 4,9-Dioxa-3,10-disiladodecan-6-one, 8-[(1E,3R)-1,3-dimethyl-4-(phenylmethoxy)-1-butenyl]-3,3-diethyl-5,7,11 -trimethyl-10,10-bis(1-methylethyl)-, (5S,7R,8R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 373645-82-0
(E)-(R)-5-Benzyloxy-2,4-dimethyl-pent-2-enal

: 905732-35-6
(E)-(2S,4R,5R,8R)-9-Benzyloxy-4,6,8-trimethyl-2-triethylsilanyloxy-5-triisopropylsilanyloxy-non-6-en-3-one

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / i-Pr₂NEt / TiCl₄ / CH₂Cl₂ / 3 h / -78 °C

2: 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 20 °C

3: CSA / CH₂Cl₂; methanol / 8 h / 0 °C

4: 2,6-lutidine / CH₂Cl₂ / 0.08 h / 0 °C

With 2,6-dimethylpyridine; camphor-10-sulfonic acid; N-ethyl-N,N-diisopropylamine; titanium tetrachloride; In methanol; dichloromethane;
DOI:10.1016/j.tetlet.2006.05.010

Reference yield:

: 143680-11-9
(E)-5-Benzyloxy-2,3-dimethyl-2-pentensaeureethylester

: 905732-35-6
(E)-(2S,4R,5R,8R)-9-Benzyloxy-4,6,8-trimethyl-2-triethylsilanyloxy-5-triisopropylsilanyloxy-non-6-en-3-one

Guidance literature:: Multi-step reaction with 6 steps

1: LAH / diethyl ether / 0.17 h / 0 °C

2: SO₃-Py; Et₃N / dimethylsulfoxide; CH₂Cl₂ / 0.5 h / 0 °C

3: 85 percent / i-Pr₂NEt / TiCl₄ / CH₂Cl₂ / 3 h / -78 °C

4: 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 20 °C

5: CSA / CH₂Cl₂; methanol / 8 h / 0 °C

6: 2,6-lutidine / CH₂Cl₂ / 0.08 h / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; pyridine-SO₃ complex; camphor-10-sulfonic acid; triethylamine; N-ethyl-N,N-diisopropylamine; titanium tetrachloride; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2006.05.010

Reference yield:

: 63930-49-4
(R)-3-(benzyloxy)-2-methylpropan-1-ol

: 905732-35-6
(E)-(2S,4R,5R,8R)-9-Benzyloxy-4,6,8-trimethyl-2-triethylsilanyloxy-5-triisopropylsilanyloxy-non-6-en-3-one

Guidance literature:: Multi-step reaction with 8 steps

1: (COCl)2; Et₃N; DMSO / CH₂Cl₂ / -78 °C

2: CH₂Cl₂ / 3 h / 20 °C

3: LAH / diethyl ether / 0.17 h / 0 °C

4: SO₃-Py; Et₃N / dimethylsulfoxide; CH₂Cl₂ / 0.5 h / 0 °C

5: 85 percent / i-Pr₂NEt / TiCl₄ / CH₂Cl₂ / 3 h / -78 °C

6: 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 20 °C

7: CSA / CH₂Cl₂; methanol / 8 h / 0 °C

8: 2,6-lutidine / CH₂Cl₂ / 0.08 h / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; oxalyl dichloride; pyridine-SO₃ complex; camphor-10-sulfonic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; titanium tetrachloride; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2006.05.010