3-(Chlorodimethylsilyl)propyl acetate

Base Information

• Chemical Name: 3-(Chlorodimethylsilyl)propyl acetate
• CAS No.: 18387-98-9
• Molecular Formula: C7H15 Cl O2 Si
• Molecular Weight: 194.733
• Hs Code.: 2931900090
• European Community (EC) Number: 242-264-1
• UNII: W2G7X884VX
• DSSTox Substance ID: DTXSID10171513
• Nikkaji Number: J266.148I
• Wikidata: Q83041587
• Mol file: 18387-98-9.mol

Synonyms:18387-98-9;3-(Chlorodimethylsilyl)propyl acetate;3-acetoxypropyl dimethylchlorosilane;3-[chloro(dimethyl)silyl]propyl acetate;3-ACETOXYPROPYLDIMETHYLCHLOROSILANE;EINECS 242-264-1;C7H15ClO2Si;C7-H15-Cl-O2-Si;SCHEMBL4951128;W2G7X884VX;DTXSID10171513;3-Acetoxypropylchlorodimethylsilane;MFCD00053898;AKOS006275120;1-Propanol, 3-(chlorodimethylsilyl)-, acetate;1-Propanol, 3-(chlorodimethylsilyl)-, 1-acetate

Chemical Property of 3-(Chlorodimethylsilyl)propyl acetate

Chemical Property:

• Vapor Pressure: 0.146mmHg at 25°C
• Boiling Point: 215.7°Cat760mmHg
• Flash Point: 84.2°C
• PSA: 26.30000
• Density: 1g/cm³
• LogP: 2.38350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 194.0529839
• Heavy Atom Count: 11
• Complexity: 136

Purity/Quality:

98%Min ^*data from raw suppliers

3-ACETOXYPROPYL DIMETHYLCHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCCC[Si](C)(C)Cl

Technology Process of 3-(Chlorodimethylsilyl)propyl acetate

There total 3 articles about 3-(Chlorodimethylsilyl)propyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

dimethylmonochlorosilane (1066-35-9) + Allyl acetate (591-87-7) → (3-acetoxypropyl)dimethylsilyl chloride (18387-98-9)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; cyclo-octa-1,5-diene; at 75 - 80 ℃; for 2h;

DOI:10.1021/ja504115d

Reference yield:

dimethylmonochlorosilane (1066-35-9) + Allyl acetate (591-87-7) → (3-acetoxypropyl)dimethylsilyl chloride (18387-98-9) + C4H9ClO2Si (6904-57-0)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In toluene; at 40 - 60 ℃; for 16h; Overall yield = 97 %Spectr.;

DOI:10.1016/j.jcat.2012.06.006

Reference yield:

3-Chloropropyl acetate (628-09-1) + dimethylsilicon dichloride (75-78-5,30107-43-8) → (3-acetoxypropyl)dimethylsilyl chloride (18387-98-9)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; zinc(II) iodide; zinc; In toluene; at 70 - 100 ℃; for 24h; Inert atmosphere;

upstream raw materials:

dimethylmonochlorosilane

Allyl acetate

3-Chloropropyl acetate

dimethylsilicon dichloride

Downstream raw materials:

2-methyl-1,3-diphenylpropan-2-ol

γ-Hydroxypropyl-benzyl-dimethylsilan

4,4,6,6-tetramethyl-5-oxa-4,6-disila-nonane-1,9-diol

Toluene-4-sulfonic acid 3-(benzyl-dimethyl-silanyl)-propyl ester

Refernces

• 1、 Pandarus, Valerica,Ciriminna, Rosaria,Gingras, Geneviève,Béland, Fran?ois,Kaliaguine, Serge,Pagliaro, Mario. "Waste-free and efficient hydrosilylation of olefins". . p. 129 - 140. Retrieved 2019/01/11.
• 2、 Moitra, Nirmalya,Ichii, Shun,Kamei, Toshiyuki,Kanamori, Kazuyoshi,Zhu, Yang,Takeda, Kazuyuki,Nakanishi, Kazuki,Shimada, Toyoshi. "Surface functionalization of silica by Si-H activation of hydrosilanes". supporting information. p. 11570 - 11573. Retrieved 2014/10/15.