Cyclohexylphosphine

Base Information

• Chemical Name: Cyclohexylphosphine
• CAS No.: 822-68-4
• Molecular Formula: C6H13P
• Molecular Weight: 116.143
• European Community (EC) Number: 812-419-3
• DSSTox Substance ID: DTXSID2073930
• Nikkaji Number: J79.970J
• Wikidata: Q82002500
• Mol file: 822-68-4.mol

Synonyms:CYCLOHEXYLPHOSPHINE;822-68-4;cyclohexylphosphane;Phosphine, cyclohexyl-;MFCD00014297;cyclohexylphoshine;Cyclohexylphospine;monocyclohexylphosphine;monocyclohexyl phosphine;SCHEMBL217375;C6H13P;SCHEMBL5778227;DTXSID2073930;C6-H13-P;FT-0632984

Chemical Property of Cyclohexylphosphine

Chemical Property:

• Appearance/Colour: colourless liquid with an offensive odour
• Vapor Pressure: 6.25mmHg at 25°C
• Boiling Point: 145 °C at 760 mmHg
• Flash Point: 41.5 °C
• PSA: 13.59000
• Density: 0,875 g/cm3
• LogP: 2.19420
• Sensitive.: air sensitive
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 116.075487412
• Heavy Atom Count: 7
• Complexity: 46.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclohexylphosphine, min. 97% (Sure/Seal(TM) bottle) ^*data from reagent suppliers

Safty Information:

• Statements: 17-20/21/22-34
• Safety Statements: 3/7-9-16-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)P

Technology Process of Cyclohexylphosphine

There total 8 articles about Cyclohexylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.13%

dicyclohexylphosphonous acid (2310-71-6) → cyclohexylphosphonic acid (1005-23-8) + cyclohexylphosphine (822-68-4)

Guidance literature:

at 250 ℃; Yields of byproduct given;

Reference yield: 33.0%

Monoethoxicarbonylcyclohexylphosphan (79564-48-0) → ethanol (64-17-5) + cyclohexylphosphine (822-68-4)

Guidance literature:

With hydrogenchloride; for 4h; Product distribution; Heating; reaction with KOH;

Reference yield:

cyclohexene (110-83-8) → cyclohexylphosphine (822-68-4)

Guidance literature:

With phosphan; Irradiation;

DOI:10.1021/ja01133a018

upstream raw materials:

cyclohexylphosphonic dichloride

cyclohexene

dicyclohexylphosphonous acid

Monoethoxicarbonylcyclohexylphosphan

Downstream raw materials:

cyclohexyl-trimethyl-phosphonium; iodide

dicyclohexylphosphine oxide

(α-Hydroxy-benzyl)-benzyl-cyclohexyl-phosphinoxid

1-cyclohexyl-2,6-diphenyl-4-phosphorinanone