Benzaldehyde, 4-bromo-2-(methylthio)-

Base Information

• Chemical Name: Benzaldehyde, 4-bromo-2-(methylthio)-
• CAS No.: 918350-11-5
• Molecular Formula: C8H7BrOS
• Molecular Weight: 231.113
• Mol file: 918350-11-5.mol

Synonyms:Benzaldehyde,4-bromo-2-(methylthio);4-bromo-2-(methylthio)benzaldehyde;4-bromo-2-(methylsulfanyl)benzaldehyde;

Chemical Property of Benzaldehyde, 4-bromo-2-(methylthio)-

Chemical Property:

• Boiling Point: 301.3±37.0 °C(Predicted)
• PSA: 42.37000
• Density: 1.57±0.1 g/cm3(Predicted)
• LogP: 2.98350

Purity/Quality:

99% ^*data from raw suppliers

4-Bromo-2-(methylsulfanyl)benzaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzaldehyde, 4-bromo-2-(methylthio)-

There total 1 articles about Benzaldehyde, 4-bromo-2-(methylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

4-bromo-2-fluorobenzaldehyde (57848-46-1) + sodium thiomethoxide (5188-07-8) → 4-bromo-2-(methylsulfanyl)benzaldehyde (918350-11-5)

Guidance literature:

In N,N-dimethyl-formamide; at -45 ℃; for 3.5h;

DOI:10.1039/c9cc00092e

Reference yield: 88.0%

4-bromo-2-(methylsulfanyl)benzaldehyde (918350-11-5) → [4-bromo-2-(methylsulfanyl)phenyl]methanol (918328-15-1)

Guidance literature:

With lithium borohydride; In tetrahydrofuran; at 20 ℃; for 3h;

Reference yield: 88.0%

4-methyl-N-(oct-1-yn-1-yl)-N-phenylbenzenesulfonamide (1116153-63-9) + 4-bromo-2-(methylsulfanyl)benzaldehyde (918350-11-5) → C29H32BrNO3S2

Guidance literature:

With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis[2-(diphenylphosphino)phenyl] ether; In acetone; at 55 ℃; for 16h;

DOI:10.1039/c7sc03795c

upstream raw materials:

4-bromo-2-fluorobenzaldehyde

sodium thiomethoxide

Downstream raw materials:

1-(4-bromophenyl)nonan-1-one

6-bromo-2-(4-bromo-2-(methylthio)phenyl)benzo[b]thiophene

4,4′-dibromo-2,2′-dimethylthio-trans-stilbene