Triethyl(fluoro)stannane

Base Information

• Chemical Name: Triethyl(fluoro)stannane
• CAS No.: 358-44-1
• Molecular Formula: C6H15 F Sn
• Molecular Weight: 224.894
• Hs Code.: 2931900090
• NSC Number: 202912
• DSSTox Substance ID: DTXSID80308278
• Mol file: 358-44-1.mol

Synonyms:358-44-1;triethyl(fluoro)stannane;triethyltin fluoride;NSC202912;Triethylfluorostannane;Stannane, triethylfluoro-;DTXSID80308278;NSC-202912

Chemical Property of Triethyl(fluoro)stannane

Chemical Property:

• Vapor Pressure: 7.07mmHg at 25°C
• Boiling Point: 142.2°C at 760 mmHg
• Flash Point: 39.8°C
• PSA: 0.00000
• LogP: 2.96110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 226.017981
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Sn](CC)(CC)F

Technology Process of Triethyl(fluoro)stannane

There total 9 articles about Triethyl(fluoro)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

tetraethyltin (597-64-8) + phosphorus pentafluoride (7647-19-0,874483-74-6) → Ethyl-tetrafluor-phosphoran (753-82-2) + triethylfluorostannane (358-44-1)

Guidance literature:

at room temp. for 26 days;

DOI:10.1021/ic50032a013

Reference yield:

tetraethyltin (597-64-8) + trityl tetrafluoroborate (341-02-6) → ethene (74-85-1) + triphenylmethane (519-73-3) + triethylfluorostannane (358-44-1)

Guidance literature:

With (C₆H₅)3CBF₄; In acetonitrile; byproducts: (C2H5)3SnF, (C6H5)3CH; 25°C; Kinetics;

DOI:10.1021/ja00752a053

Reference yield:

N-(triethylstannyl)maleimide (65284-41-5) + benzoyl chloride (98-88-4) → triethylfluorostannane (358-44-1) + N-benzoylmaleimide (77303-07-2)

Guidance literature:

With potassium fluoride; In ethanol; water; addn. of org. compd. to Sn-compd. (vac.), sealing, reacting (room temp., 1 d), sepn. of org. compd. on filtration (Ar atmosphere), addn. of aq.-alcoholic soln. of KF;

upstream raw materials:

triethyltin bromide

potassium fluoride

chlorotriethylstannane

tetraethyltin

Downstream raw materials:

n-Propyl-triaethyl-zinn

Refernces

• 1、 Treichel,Goodrich, Ruth A.. "The reaction of phosphorus pentafluoride and tetraalkyltin compounds". . p. 1424 - 1428. Retrieved 2008/10/08.