1,4-Bis(trimethylsilyl)-2-butene

Base Information

Chemical Name:1,4-Bis(trimethylsilyl)-2-butene
CAS No.:16054-35-6
Molecular Formula:C10H24 Si2
Molecular Weight:200.472
Hs Code.:2931900090
Nikkaji Number:J1.260.209J,J700.877E
Mol file:16054-35-6.mol

Synonyms:1,4-Bis(trimethylsilyl)-2-butene;2,7-Disilaoct-4-ene, 2,2,7,7-tetramethyl-, (E)-;16054-35-6;trimethyl-[(E)-4-trimethylsilylbut-2-enyl]silane;Silane, 2-butene-1,4-diylbis[trimethyl-;1,4-bis(trimethylsilyl)butene-2;DHTZZPHEAHKIBY-BQYQJAHWSA-N;(E)-1,4-Bis(trimethylsilyl)-2-butene;Silane, 2-butene-1,4-diylbis[trimethyl-, (E)-;Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane #

Suppliers and Price of 1,4-Bis(trimethylsilyl)-2-butene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1,4-Bis(trimethylsilyl)-2-butene

Chemical Property:

Vapor Pressure:1.11mmHg at 25°C
Boiling Point:182.3°C at 760 mmHg
Flash Point:44.6°C
PSA：0.00000
Density:0.774g/cm³
LogP:4.21900
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:200.14165383
Heavy Atom Count:12
Complexity:128

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)CC=CC[Si](C)(C)C
Isomeric SMILES:C[Si](C)(C)C/C=C/C[Si](C)(C)C

Technology Process of 1,4-Bis(trimethylsilyl)-2-butene

There total 3 articles about 1,4-Bis(trimethylsilyl)-2-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 754-05-2
ethenyltrimethylsilane

: 18178-59-1
(E)-1,2-bis(trimethylsilyl)ethene

: 74-85-1
ethene

: 107-46-0
Hexamethyldisiloxane

: 5654-07-9
1,1-bis(trimethylsilyl)ethylene

: 16054-34-5
(Z)-1,4-bis(trimethylsilyl)-2-butene

: 16054-35-6
(E)-1,4-bis(trimethylsilyl)but-2-ene

Guidance literature:: With tris(triphenylphosphine)ruthenium(II) chloride; air; In benzene; at 130 ℃; for 48h; Product distribution; Mechanism; other ruthenium complexes;
DOI:10.1016/0022-328X(94)84049-0

Reference yield:

: 754-05-2
ethenyltrimethylsilane

: 16054-34-5
(Z)-1,4-bis(trimethylsilyl)-2-butene

: 16054-35-6
(E)-1,4-bis(trimethylsilyl)but-2-ene

: 53304-31-7
but-3-ene-1,3-diylbis(trimethylsilane)

: 110434-24-7,128815-35-0
3-<1-(trimethylsilyl)vinyl>-1-cyclohexene

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; diethylaluminium chloride; cyclohexa-1,3-diene; triphenylphosphine; In toluene; at 50 ℃; for 48h; Yield given. Yields of byproduct given;
DOI:10.1021/jo00236a037

Reference yield:

: 1165952-91-9
cyclohexa-1,3-diene

: 754-05-2
ethenyltrimethylsilane

: 16054-34-5
(Z)-1,4-bis(trimethylsilyl)-2-butene

: 16054-35-6
(E)-1,4-bis(trimethylsilyl)but-2-ene

: 53304-31-7
but-3-ene-1,3-diylbis(trimethylsilane)

: 110434-24-7,128815-35-0
3-<1-(trimethylsilyl)vinyl>-1-cyclohexene

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; diethylaluminium chloride; triphenylphosphine; In toluene; at 50 ℃; for 48h; Product distribution; other ligands, var. P/Ni and Al/Ni ratios, var. reaction times;
DOI:10.1021/jo00236a037