Boron chloride oxide

Base Information

• Chemical Name: Boron chloride oxide
• CAS No.: 23361-55-9
• Molecular Formula: BClO
• Molecular Weight: 62.2634
• DSSTox Substance ID: DTXSID10177919
• Wikidata: Q83048265
• Mol file: 23361-55-9.mol

Synonyms:Boron chloride oxide;23361-55-9;OBCl;chlorooxoborane;DTXSID10177919

Chemical Property of Boron chloride oxide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 61.9730725
• Heavy Atom Count: 3
• Complexity: 12.3

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(=O)Cl

Technology Process of Boron chloride oxide

There total 8 articles about Boron chloride oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

boron trichloride (10294-34-5) + tributyl(cyclohex-2-en-1-yl)stannane (112520-99-7,1177092-71-5) + propionaldehyde (123-38-6) → boron oxychloride (23361-55-9) + C2H5CHClCHCHCH(CH2)2CH2 + tributyltin chloride (1461-22-9)

Guidance literature:

In dichloromethane; (N2); addn. of Sn-compd. to mixt. of 1 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature; various product ratio for various conditions; treatment with sat. aq. NH4Cl;

DOI:10.1016/0022-328X(90)85025-T

Reference yield: 78.0%

boron trichloride (10294-34-5) + tributyl(cyclohex-2-en-1-yl)stannane (112520-99-7,1177092-71-5) + propionaldehyde (123-38-6) → boron oxychloride (23361-55-9) + C2H5CHClCHCHCH(CH2)2CH2 + 9-chloro-2,4-diethyl-cis-3-oxabicyclo{3.3.1}nonane

Guidance literature:

In dichloromethane; (N2); addn. of Sn-compd. to mixt. of 2.2 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature; treatment with sat. aq. NH4Cl;

DOI:10.1016/0022-328X(90)85025-T

Reference yield: 68.0%

allyltributylstanane (24850-33-7) + boron trichloride (10294-34-5) + propionaldehyde (123-38-6) → boron oxychloride (23361-55-9) + tributyltin chloride (1461-22-9) + 4-chloro-2,6-diethyltetrahydropyran (88404-79-9)

Guidance literature:

In dichloromethane; (N2); addn. of Sn-compd. to mixt. of 2.2 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature; treatment with sat. aq. NH4Cl;

DOI:10.1016/0022-328X(90)85025-T

upstream raw materials:

phosphorus pentachloride

chlorodimethoxyborane

allyltributylstanane

boron trichloride

Downstream raw materials:

boron trichloride