2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester

Base Information

• Chemical Name: 2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester
• CAS No.: 113274-26-3
• Molecular Formula: C6H13 N3 O3
• Molecular Weight: 175.188
• Mol file: 113274-26-3.mol

Synonyms:2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester

Chemical Property of 2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester

Chemical Property:

• PSA: 74.49000
• LogP: 0.43420

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester

There total 1 articles about 2-Triazene-1-carboxylic acid, 3-(2-hydroxyethyl)-1-methyl-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.5%

1-<2-(tert-butyldimethylsiloxy)-ethyl>-3-carbethoxy-3-methyltriazene (113274-23-0) → 3-carbethoxy-2-(hydroxyethyl)-3-methyltriazene (113274-26-3)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 35 ℃; for 0.5h;

DOI:10.1021/jo00242a022

Reference yield:

3-carbethoxy-2-(hydroxyethyl)-3-methyltriazene (113274-26-3) → Ethyl N-methylcarbamate (105-40-8) + ethylene glycol (107-21-1) + acetaldehyde (75-07-0,9002-91-9)

Guidance literature:

With water; In acetonitrile; at 70 ℃; Rate constant; Mechanism; Product distribution; hydrolytic decomposition in acidic and neutral buffers; pH-dependence of the rate of decomposition; solvent deuterium isotope effect (k_H2O/k_D2O);

DOI:10.1021/jo00028a047

Reference yield:

1-(2-hydroxyethyl)-3-methyl-3-carbethoxytriazene (113274-26-3) → Ethyl N-methylcarbamate (105-40-8) + ethylene glycol (107-21-1) + acetaldehyde (75-07-0,9002-91-9)

Guidance literature:

With sodium phosphate buffer; (2E)-but-2-enedioic acid; sodium chloride; In water; at 37 ℃; for 48h; pH=7.5; Kinetics;

DOI:10.1021/tx9500742

upstream raw materials:

1-<2-(tert-butyldimethylsiloxy)-ethyl>-3-carbethoxy-3-methyltriazene

Downstream raw materials:

Ethyl N-methylcarbamate

ethylene glycol

acetaldehyde

ethanol